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Table 1
New or modified photodissociation processes included in the model (update of Hébrard et al. 2012).
| Reaction | Reaction | Quantum yield q, |
| number | dissociation limit (nm) | |
|
|
||
| J1 | C2H2 + hν → C2H + H | 1.0, 215 |
| J2 | C3 + hν → C2 + C | 1.0, 161 |
| J3 | c-C3H + hν → C3 + H | 1.0, 359 |
| J4 | l-C3H + hν → C3 + H | 1.0, 374 |
| J5a | c-C3H2 + hν → l-C3H + H | 0.3, 266 |
| J5b | c-C3H2 + hν → c-C3H + H | 0.3, 274 |
| J5c | c-C3H2 + hν → C3 + H2 | 0.4, 289 |
| J6a | l-C3H2 + hν → l-C3H + H | 0.3, 308 |
| J6b | l-C3H2 + hν → c-C3H + H | 0.3, 318 |
| J6c | l-C3H2 + hν → C3 + H2 | 0.4, 325 |
| J7a | t-C3H2 + hν → l-C3H + H | 0.5, 298 |
| J7b | t-C3H2 + hν → c-C3H + H | 0.5, 307 |
| J8a | C3H3 + hν → t-C3H2 + H | 0.5, 292 |
| J8b | C3H3 + hν → c-C3H2 + H | 0.5, 330 |
| J9a | CH2CCH2 + hν → C2H2 + 3CH2 | 0.2, 280 |
| J9b | CH2CCH2 + hν → C3H3 + H | 0.7, 315 |
| J9c | CH2CCH2 + hν → l-C3H2 + H2 | 0.05, 326 |
| J9d | CH2CCH2 + hν → c-C3H2 + H2 | 0.05, 390 |
| J10a | CH3C2H + hν → C2H + CH3 | 0.07, 227 |
| J10b | CH3C2H + hν → C2H2 + 3CH2 | 0.03, 276 |
| J10c | CH3C2H + hν → C3H3 + H | 0.80, 309 |
| J10d | CH3C2H + hν → l-C3H2 + H2 | 0.05, 320 |
| J10e | CH3C2H + hν → c-C3H2 + H2 | 0.05, 382 |
| J11a | C3H5 + hν → C2H2 + CH3 | 0.16, 450 |
| J11b | C3H5 + hν → CH2CCH2 + H | 0.42, 505 |
| J11c | C3H5 + hν → CH3C2H + H | 0.42, 518 |
| J12a | C3H6 + hν → CH2CCH2 + H + H | 0.05, λ < 160 |
| 0.05, λ ∈ [160,197] | ||
| J12b | C3H6 + hν → CH3C2H + H + H | 0.05, λ < 160 |
| 0.05, λ ∈ [160,199] | ||
| J12c | C3H6 + hν → C2H2 + CH3 + H | 0.7, λ < 160 |
| 0.2, λ ∈ [160,209] | ||
| J12d | C3H6 + hν → C3H3 + H2 + H | 0.2, λ < 160 |
| 0.2, λ ∈ [160,222] | ||
| J12e | C3H6 + hν → C2H3 + CH3 | 0.0, λ < 160 |
| 0.3, λ ∈ [160,281] | ||
| J12f | C3H6 + hν → C3H5 + H | 0.0, λ < 160 |
| 0.2, λ ∈ [160,324] | ||
| J13 | C3H7 + hν → C3H6 + H | 1.0 , 867 |
| J14a | HC3N + hν → CN + C2H | 0.3, 185 |
| J14b | HC3N + hν → HCN + C2 | 0.1, 193 |
| J14c | HC3N + hν → C3N + H | 0.3, 220 |
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