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Table 1
Determined rotational and centrifugal distortion parameters.
| Parameters | DCONH2 | cis − HCONHD | trans − HCONHD | HCOND2 |
|
|
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| A/MHz | 54 947.57729(32) | 61 345.06804(79) | 71 180.6464(10) | 59 716.2039(11) |
| B/MHz | 11 372.988736(77) | 11 009.914332(79) | 10 473.401540(85) | 10 193.55866(10) |
| C/MHz | 9419.700841(75) | 9334.077245(79) | 9132.395384(83) | 8710.364411(99) |
| ΔJ/kHz | 7.553397(62) | 8.223993(66) | 6.132655(63) | 6.275856(75) |
| ΔJK/kHz | –33.67978(44) | –49.38969(98) | –47.6150(12) | –29.0401(10) |
| ΔK/kHz | 664.6759(28) | 829.104(25) | 1193.824(53) | 677.538(32) |
| δJ/kHz | 1.790970(16) | 1.769062(27) | 1.107008(29) | 1.244239(32) |
| δK/kHz | 31.47873(85) | 37.0620(26) | 29.5820(41) | 31.0425(40) |
| ΦJ/Hz | 0.010585(16) | 0.012694(19) | 0.006648(18) | 0.007697(19) |
| ΦJK/Hz | 0.08780(39) | 0.1108(28) | 0.0 | 0.0521(29) |
| ΦKJ/Hz | –3.1388(19) | –4.244(10) | –3.8197(58) | –2.205(10) |
| ΦK/Hz | 25.0445(85) | 37.73(19) | 54.05(73) | 0.0 |
| φJ/Hz | 0.0049033(55) | 0.0053569(93) | 0.0027398(93) | 0.0030776(93) |
| φJK/Hz | 0.08197(43) | 0.0883(12) | 0.0445(17) | 0.0648(13) |
| φK/Hz | 6.239(11) | 9.47(11) | 9.232(27) | 6.88(13) |
| LKJ/mHz | –0.00873(35) | –0.0347(12) | –0.0244(15) | 0.0 |
| LKKJ/mHz | 0.1379(11) | 0.3115(75) | 0.0 | 0.0 |
| χaa/MHz | 1.889(23) | 1.973(48) | 2.025(61) | 1.941(60) |
| χbb–χaa/MHz | 5.896(19) | 5.864(21) | 5.861(27) | 5.869(36) |
| Nmbr of transitions | 1283 | 655 | 597 | 445 |
| σFIT/kHz | 27 | 26 | 30 | 28 |
| σ W | 0.696 | 0.651 | 0.647 | 0.744 |
| J max , K a,max | 58, 29 | 50, 23 | 50, 20 | 54, 18 |
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