Fig. 6

Formaldehyde thermal evolution as a function of temperature in water ice containing CH3NH214N (triangle), and 15N (square) (H2O/CH3NH2/CH2O = 1/2/0.1). The rate coefficients are given in the form k = ν0exp( − E/RT), where T is the ice temperature (K), ν0 the pre-exponential factor (s-1), and E the activation energy (J mol-1). The corresponding rate coefficients are k14N = 1.5 ± 0.1 × 10-2exp( − 1100 ± 50/RT) and k15N = 2.6 ± 0.3 × 10-2exp( − 1800 ± 80/RT).
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