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Table B.1

List of symbols and their explanation.

Symbol Parameter

ad diameter of interstellar grains (in μm)
ds size of each site (in Å )
Ed barrier energy against diffusion of a considered species (in K)
Eb barrier energy against desorption of a considered species (in K)
Ea activation energy of the CO and H2CO hydrogenation reactions (in K)
Fpor fraction of the grain surface occupied by the pores
Fnp fraction of the grain surface occupied by the non-porous surface
Fed fraction of the grain surface occupied by the edge porous sites
rd radius of interstellar grains (in μm)
nd density of interstellar grains (in cm-3)
Npore number of sites occupied by each pore
Ns number of sites of the considered layer
nH total density of H nuclei (in cm-3)
ng gas phase density of a considered species (in cm-3)
Pnp surface population of a considered species in the non-porous surface (in monolayers)
Ppor surface population of a considered species in the pores (in monolayers)
Racc accretion rate of a considered species (in s-1)
Rhop hopping rate from site to site of a considered species (in s-1)
Rdiff diffusion rate of a considered species (in s-1)
Rr,np reaction rate of a considered reaction in the non-porous surface (in s-1)
Rr,por reaction rate of a considered reaction in the pores (in s-1)
Rev evaporation rate of a considered species (in s-1)
S sticking coefficient of a considered species
σd cross section of interstellar grains (in cm2)
Tg gas temperature (in K)
Td dust temperature (in K)
v thermal velocity of a considered species in the gas phase (in cm s-1)
Xd abundance of interstellar grains relative to H nuclei
Xg abundance relative to H nuclei of a considered species in the gas phase
Xm abundance relative to H nuclei of a considered species on grain mantles
ζ cosmic rays ionization rate (in s-1)

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