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Table B.5
Spectroscopic parameters of the vibrationally excited states.
| Parameters | v27 = 1 | v26 = 1 | v25 = 1 | v24 = 1 | v27 = 2 |
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| Energy (in cm-1)a | 184.7 | 225.6 | 238.2 | 282.7 | 370.8 |
| A (in MHz) | 8287.8917(20) | 8380.6862(41) | 8322.3521(34) | 8310.4161(31) | 8247.6331(42) |
| B (in MHz) | 3996.55361(23) | 3988.52138(32) | 3985.77815(27) | 3987.76717(24) | 4008.61501(35) |
| C (in MHz) | 2944.43923(13) | 2949.48281(25) | 2944.38523(23) | 2947.15900(16) | 2943.42120(27) |
| ΔJ (in kHz) | 1.011705(75) | 1.026474(92) | 0.987738(82) | 0.993488(72) | 1.020469(95) |
| ΔJK (in kHz) | 10.23071(43) | 11.39062(74) | 10.78368(67) | 10.73352(53) | 9.61190(83) |
| ΔK (in kHz) | –5.6202(79) | –1.140(19) | –3.594(15) | –3.908(14) | –7.125(20) |
| δJ (in kHz) | 0.248268(38) | 0.233476(52) | 0.235779(40) | 0.238122(35) | 0.259062(53) |
| δK (in kHz) | 6.62698(75) | 7.1830(14) | 6.8368(13) | 6.7900(10) | 6.3394(13) |
| HJ (in Hz) | 0.001012(14) | 0.0b | 0.0005169(72) | 0.0004899(55) | 0.0003095(90) |
| HJK (in Hz) | 0.07024(39) | 0.05593(29) | 0.05454(26) | 0.07110(35) | 0.04602(73) |
| HKJ (in Hz) | –0.15863(93) | –0.00724(35) | –0.02400(36) | –0.09684(89) | –0.1491(21) |
| HK (in Hz) | 0.0b | 0.0b | 0.0b | 0.0b | 0.0b |
| hJ (in Hz) | 0.0002927(77) | –0.0002907(39) | 0.0b | 0.0b | 0.0b |
| hJK (in Hz) | 0.03793(12) | 0.01795(23) | 0.02145(23) | 0.03282(17) | 0.03283(28) |
| hK (in Hz) | 0.1567(21) | 0.0b | 0.0b | 0.1421(16) | 0.0452(38) |
| LJJK (in mHz) | –0.000568(22) | ||||
| lKJ (in mHz) | –0.00399(18) | ||||
| Number of lines | 679 | 465 | 453 | 505 | 412 |
| Frequency max (in GHz) | 605 | 465 | 465 | 465 | 465 |
| JMax, Ka,Max | 99, 35 | 78, 30 | 78, 35 | 78, 35 | 78, 31 |
| Standard deviation of the fit (in kHz) | 77 | 89 | 84 | 81 | 88 |
| Weighted deviation of fit | 0.96 | 1.18 | 1.04 | 0.87 | 1.06 |
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