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Table 1
Experimental and calculated lifetimes obtained in the present work for selected levels within the 4d7(4F)5p configuration of Rh II.
| Level | Energy (cm-1)a | Excitation | Detection (nm) | τexp(ns) | τcalc(ns) | ||||
| Origin (cm-1)a | λvac (nm) | Conversionb | |||||||
|
|
|||||||||
z 5F |
56547.3 | 18540.4 | 263.03 | 3ω +2S | 252 | 3.9 ± 0.5 | 4.4 | ||
z 5F |
57020.8 | 18540.4 | 259.80 | 3ω +2S | 249 | 3.8 ± 0.3 | 4.0 | ||
z 5F |
58358.5 | 19792.4 | 259.22 | 3ω +2S | 251 | 3.8 ± 0.3 | 4.2 | ||
z 5F |
59698.6 | 20646.9 | 255.99 | 3ω +2S | 251 | 3.8 ± 0.3 | 4.2 | ||
| z 5D |
59161.5 | 16884.8 | 236.47 | 3ω +S | 246/304 | 3.3 ± 0.2 | 3.9 | ||
| z 5D |
60448.4 | 18540.4 | 238.55 | 3ω +S | 246/303 | 3.4 ± 0.4 | 3.9 | ||
| z 5D |
61355.9 | 19792.4 | 240.52 | 3ω +S | 246/302 | 3.7 ± 0.5 | 4.0 | ||
z 5G |
59702.4 | 16884.8 | 233.48 | 3ω +S | 233 | 3.0 ± 0.2 | 3.1 | ||
| z 5G |
59729.4 | 16884.8 | 233.33 | 3ω +S | 243 | 3.5 ± 0.2 | 4.0 | ||
| z 5G |
61173.1 | 16884.8 | 225.72 | 3ω +S | 242 | 3.3 ± 0.2 | 3.5 | ||
| z 5G |
61939.8 | 18540.4 | 230.35 | 3ω +S | 242 | 3.3 ± 0.3 | 3.6 | ||
| z 5G |
62288.3 | 20646.9 | 240.07 | 3ω +S | 243/235 | 3.3 ± 0.3 | 3.6 | ||
| z 3G |
62194.4 | 16884.8 | 220.64 | 3ω | 272 | 3.2 ± 0.2 | 3.5 | ||
| z 3G |
63959.5 | 18540.4 | 220.10 | 3ω | 274 | 3.4 ± 0.2 | 3.7 | ||
| z 3G |
65321.2 | 18540.4 | 213.69 | 3ω | 274 | 2.0 ± 0.2 | 2.4 | ||
| z 3F |
62326.1 | 16884.8 | 219.99 | 3ω | 271 | 2.4 ± 0.2 | 2.8 | ||
| z 3F |
63454.9 | 18540.4 | 222.58 | 3ω | 278 | 2.3 ± 0.3 | 2.5 | ||
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