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Table 2:

Relative NIR clathrate hydrate and methane ice integrated intensitiesa.
Dominant transitions Clathrate (5.6 K) Methane iceb
$3\nu_4$ 0.063 $\sim $0.054c
$\nu _2+2\nu _4$ 0.010 0.013
$\nu _1+\nu _4$ 0.511 0.524
$\nu _3+\nu _4$ 1.0a 1.0a
$\nu _2+\nu _3$ 0.099 0.095
$\nu _3+2\nu _4$ 0.014 0.014
$2\nu_2+2\nu_4$ 0.004 $\sim $0.004d
$\nu _2+\nu _3+\nu _4$ 0.028 0.029
$2\nu _3$ 0.042 0.061

Notes.  (a) Normalised to the $\nu _3+\nu _4$ transitions; (b) Brunetto et al. (2008) at 16 K; (c) intensity before normalisation estimated from the ratio of absorption coefficient of $(\nu_1+\nu_4)$/$3\nu_4$ from Quirico & Schmitt (1997) at 21 K, assuming the same line width for both transitions; (d)  integrated intensity before normalisation estimated from the spectrum of the blended $(2\nu_2+2\nu_4)$/ $(\nu_3+2\nu_4)$ lines from Fig. 2b in Quirico & Schmitt (1997) at 21 K.


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