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Table 2:

Comparison of level energies (Ry) for Si II.

Level
Exp. AST1 AST2 AST3 AST4 AST5 AST6 AST7 AST8 AST9
    Difference from experiment(%)
3s23p 2P $^\circ _{1/2}$ 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
3s23p 2P $^\circ _{3/2}$ 0.002618 -18.8 -17.8 -14.8 -15.0 -15.0 -15.0 -15.1 0.19 -0.12
3s3p2 4P1/2 0.390244 -7.86 -17.4 -11.3 -11.3 -10.9 -10.9 -10.6 -7.06 -7.62
3s3p2 4P3/2 0.391231 -7.90 -17.4 -11.4 -11.3 -10.9 -10.9 -10.6 -7.01 -7.57
3s3p2 4P5/2 0.392828 -7.96 -17.4 -11.4 -11.3 -10.9 -10.9 -10.6 -6.92 -7.48
3s3p2 2D3/2 0.504016 14.5 2.42 1.03 1.00 1.18 1.18 1.42 -0.01 -0.25
3s3p2 2D5/2 0.504160 14.4 2.40 1.01 0.98 1.15 1.16 1.39 -0.02 -0.27
3s24s 2S1/2 0.596884 -0.53 3.31 -0.39 -0.49 -0.59 -0.54 -0.32 15.3 -4.64
3s3p2 2S1/2 0.698626 0.69 1.64 3.23 3.25 3.46 3.46 3.60 2.73 1.78
3s23d 2D3/2 0.722986 35.3 -2.37 1.19 1.13 1.14 1.17 1.29 11.1 10.3
3s23d 2D5/2 0.723136 35.2 -2.39 1.17 1.12 1.12 1.16 1.28 11.1 10.3
3s24p 2P $^\circ _{1/2}$ 0.739870 22.0 3.40 6.77 6.83 7.03 7.07 6.81 13.9 13.7
3s24p 2P $^\circ _{3/2}$ 0.740416 22.3 3.41 6.82 6.87 7.08 7.12 6.86 14.0 13.9
3s3p2 2P1/2 0.763660 0.75 5.74 5.52 5.49 5.68 5.71 5.74 4.20 5.01
3s3p2 2P1/2 0.765503 0.69 5.68 5.47 5.44 5.64 5.66 5.70 4.21 5.04

Source LaTeX | All tables | In the text

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