Open Access

Table B.3

Reactions from KIDA corrected with the endothermicity found by Tinacci et al. (2023).

Reaction α [cm3.s−1] β γKIDA [K] γcorrected [K]
C2H3+CH3+H2CCH++H2+HMathematical equation: $\[\mathrm{C}_{2} \mathrm{H}_{3}+\mathrm{CH}_{3}^{+} \rightarrow \mathrm{H}_{2} \mathrm{CCH}^{+}+\mathrm{H}_{2}+\mathrm{H}\]$ 9.50 × 10−11 −0.5 0.0 1878
CH4 + H2CCC → CH3 + CH2CCH 5.90 × 10−11 0.0 0.0 2210
H2 + C3H2 → H + CH2CCH 3.74 × 10−12 2.0 1740 8766
CH2 + C4H2 → CH3 + C4H 2.16 × 10−11 0.0 2160 11400
H2+C4H2+H+C4H3+Mathematical equation: $\[\mathrm{H}_{2}+\mathrm{C}_{4} \mathrm{H}_{2}^{+} \rightarrow \mathrm{H}+\mathrm{C}_{4} \mathrm{H}_{3}^{+}\]$ 1.00 × 10−9 0.0 2000 5339
H2 + C5H → H + C5H2 1.14 × 10−11 0.0 950 9578
H2 + C5 → H + C5H 1.60 × 10−10 0.0 1420 9780

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