Table A.2
Reaction list (only a sample is shown).
| Bimolecular reactions | ||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Reaction | α (cm3 s−1) | β | γ (K) | Temperature range (K) | Error | Ref. | ||||||||||
| H + CH → C + H2 | 2.0 × 10−10 | 0.0 | 0 | 1500-2500 | A | (62) | ||||||||||
| O2 + C4H5 → HO2 + C4H4 | 1.2 × 10−12 | 0.21 | 6420 | 300-2000 | B | (748) | ||||||||||
| HCCO + CH → CO + C2H2 | 8.3 × 10−11 | 0.0 | 0 | 300-2000 | C | (172) | ||||||||||
| NH2 + OH → NH + H2O | 3.6 × 10−13 | 1.97 | −1130 | 300-3000 | A | (463) | ||||||||||
| H2S + CH → H2CS + H | 2.8 × 10−10 | 0.0 | 0 | 330-330 | A | (267) | ||||||||||
| Pressure-dependent reactions | ||||||||||||||||
| k0 | k∞ | Fc | k0 | k∞ | Fc | |||||||||||
| Reaction | α | β | γ | α | β | γ | A | B | M | Temperature range (K) | Error | Ref. | ||||
| H + CH3 + M = CH4 + M | 5.9 × 10−29 | −1.8 | 0 | 3.5 × 10−10 | 0.0 | 0 | 0.611 | −1.4 × 10− 4 | Ar | 300-1000 | 300-2000 | 300-2000 | A | (62) | ||
| CH3 + CH3 + M → C2H6 + M | 1.6 × 10−24 | −7.0 | 1390 | 6.0 × 10−11 | 0.0 | 0 | 0.516 | −2.2 × 10−4 | Ar | 300-2000 | 300-2000 | 300-2000 | A | (62) | ||
| O2 + H + M → HO2 + M | 4.8 × 10−32 | −1.29 | 0 | 5.3 × 10−11 | 0.604 | −121 | 0.458 | N2 | 300-2000 | 300-2000 | A | (976) | ||||
| N + O + M → NO + M | 5.5 × 10−33 | 0.0 | −155 | N2 | 196-298 | C | (131) | |||||||||
| S + H2S + M → H2S2 + M | 6.7 × 10−31 | −1.612 | 840 | 1.6 × 10−13 | 1.28 | −240 | 0.810 | −5.8 × 10−4 | Ar | 291-1042 | 291-1042 | 291-1042 | A | (290) | ||
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