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Table A.3

Uptake coefficients for heterogeneous reactions involving chlorinated species.

Label Reaction Uptake coefficient Reference
γ1 6 H2O + dust → Cl + 6 H2O 0.1 ×6.3 × 10−2 × jClO(z) [3] based on [20] and [21]
γ2 2 HCl + dust → 2H MPM(0.2, 2.03×103, 12.30×103) [3] based on [6] and [7]
γ3 HCl + water ice → H + Cl or H MPM(0.09, 8.33×108, 30.50×103) × (1 - θLang) [3] based on [8] and [9]
γ4 Cl2 + dust → Ø 1×10−3 [2] (upper limit)
γ5 ClO + water ice → O 1×10−4 [2] (upper limit)

Notes. The MPM function is MPM(A, AdesAR$\frac{A_{\text{des}}}{A_{\text{R}}}$, ΔE) = A/[1 + AdesAR$\frac{A_{\text{des}}}{A_{\text{R}}} \times \exp{\left ( -\Delta E / RT(z) \right )}$], with Ades the pre-exponential factor of the adsorbed molecule (s−1), AR the pre-exponential factor of the adsorbed molecule ionisation (s−1), and ΔE the difference in the activation energies from the Arrhenius equations controlling the adsorption of molecules onto the solid and the ionisation of the adsorbed molecule onto the solid surface (J.mol−1). R is the ideal gas constant and T(z) the atmospheric temperature at altitude z (Berland et al. 1997; Taysum et al. 2024).

θLang is the water ice surface coverage as defined by Kippenberger et al. (2019): θLang=KLang[HCl]1+KLang[HCl]$\theta_{\text{Lang}} = \frac{K_{\text{Lang}}[\text{HCl}]}{1+K_{\text{Lang}}[\text{HCl}]}$, with KLang = 9.6 × 10−11 cm3.mol−1 and [HCl] the number density of HCl (mol.cm−3).

[20] - Zhang et al. (2022), [21] - Seisel et al. (2005). For other references, see footnote of Table A.2

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