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Table A.1

Description of the opacities used to calculate temperature profiles and emission spectra.

Species Source Line list Line List Reference
Al DACE VALD Ryabchikova et al. (2015)
AlH HELIOS-K AlHambra Yurchenko et al. (2018d)
AlO HELIOS-K ATP Patrascu et al. (2015)
C DACE Kurucz Kurucz (1992)
C2 DACE 8states Yurchenko et al. (2018c)
C2H2 DACE aCeTY Chubb et al. (2020)
C2H4 DACE MaYTY Mant et al. (2018)
Ca DACE VALD Ryabchikova et al. (2015)
CaH HELIOS-K MoLLIST Li et al. (2012); Bernath (2020)
CaO HELIOS-K VBATHY Yurchenko et al. (2016)
CaOH DACE OYT6 Owens et al. (2022)
CH DACE MoLLIST Masseron et al. (2014); Bernath (2020)
CH3 DACE AYYJ Adam et al. (2019)
CH4 DACE YT34to10 Yurchenko et al. (2017)
CN HELIOS-K Trihybrid Syme & McKemmish (2021)
CO DACE Li2015 Li et al. (2015)
CO2 DACE HITEMP & UCL-4000c Rothman et al. (2010); Yurchenko et al. (2020)
CS DACE JnK Paulose et al. (2015)
Fe DACE VALD Ryabchikova et al. (2015)
FeH DACE MoLLIST Dulick et al. (2003)
H2+ DACE ADJSAAM Amaral et al. (2019)
H2CO DACE AYTY Al-Refaie et al. (2015)
H2O DACE POKAZATEL Polyansky et al. (2018)
H2O2 DACE APTY Al-Refaie et al. (2016)
H2S DACE AYT2 Azzam et al. (2016)
H3O+ DACE eXeL Yurchenko et al. (2020)
HCN HELIOS-K Harris Barber et al. (2014)
HNO3 DACE AIJS Pavlyuchko et al. (2015)
HS HELIOS-K GYT Gorman et al. (2019)
K DACE VALD Ryabchikova et al. (2015)
KOH DACE OYT4 Owens et al. (2021)
Mg DACE Kurucz Kurucz (1992)
MgH HELIOS-K MoLLIST GharibNezhad et al. (2013); Bernath (2020)
MgO HELIOS-K LiTY Li et al. (2019)
N DACE VALD Ryabchikova et al. (2015)
N2 DACE WCCRMT Western et al. (2018)
N2O DACE HITEMP2019 Hargreaves et al. (2019)
Na DACE VALD Ryabchikova et al. (2015)
NaH HELIOS-K Rivlin Rivlin et al. (2015)
NaO DACE NaOUCMe Mitev et al. (2022)
NaOH DACE OYT5 Owens et al. (2021)
NH DACE MoLLIST Fernando et al. (2018)
NH3 DACE CoYuTe Coles et al. (2019)
NO DACE XABC Wong et al. (2017); Qu et al. (2021)
NO2 DACE HITEMP2019 Hargreaves et al. (2019)
NS DACE SNaSH Yurchenko et al. (2018a)
OH DACE HITEMP Rothman et al. (2010)
OH+ DACE MoLLIST Hodges & Bernath (2017)
P DACE VALD Ryabchikova et al. (2015)
P2H2 DACE OY-trans Owens & Yurchenko (2019)
PC DACE MoLLIST Ram et al. (2014); Qin et al. (2021)
PH HELIOS-K LaTY Langleben et al. (2019)
PH3 DACE SAlTY Sousa-Silva et al. (2015)
PN DACE YYLT Yorke et al. (2014)
PO DACE POPS Prajapat et al. (2017)
PS HELIOS-K POPS Prajapat et al. (2017)
S DACE VALD Ryabchikova et al. (2015)
SH DACE GYT Gorman et al. (2019)
Si DACE VALD Ryabchikova et al. (2015)
SiH HELIOS-K Sightly Yurchenko et al. (2018b)
SiH2 HELIOS-K CATS Clark et al. (2020)
SiH4 DACE OY2T Owens et al. (2017)
SiN DACE SiNfull Semenov et al. (2022)
SiO HELIOS-K SiOUVenIR Yurchenko et al. (2022)
SiO2 DACE OYT3 Owens et al. (2020)
SiS DACE UCTY Upadhyay et al. (2018)
SO DACE SOLIS Brady et al. (2024)
SO2 ExoMol ExoAmes Underwood et al. (2016a)
SO3 ExoMol UYT2 Underwood et al. (2016b)
Ti DACE VALD Ryabchikova et al. (2015)
TiH HELIOS-K MoLLIST Burrows et al. (2005); Bernath (2020)
TiO HELIOS-K Toto McKemmish et al. (2019)
Scattering and Continuum
CO, CO2, CH4, H Scattering
H2, H2O, N2, O2 Scattering
H– Continuum (bf & ff) John (1988); Gray (2008)
H2–H2 petitRADTRAN CIA Borysow et al. (2001); Borysow (2002)
CO2 – CO2 petitRADTRAN CIA Karman et al. (2019)
O2–O2 petitRADTRAN CIA Karman et al. (2019)
N2–H2 petitRADTRAN CIA Karman et al. (2019)
N2–N2 petitRADTRAN CIA Karman et al. (2019)

c We use HITEMP2010 for temperature profiles and UCL-4000 for emission spectra; d.

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