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Fig. 1.

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Time resolved numerical solution of the reaction rates for the ionisation fractions of hydrogen, oxygen, and nitrogen (Eqs. (3)–(10)). The initial conditions at t0 = 0 were n e init = 2000 cm 3 $ n_{\mathrm{e}}^{\mathrm{init}} = 2000\,\mathrm{cm}^{-3} $, x e init = 0.1 $ x_{\mathrm{e}}^{\mathrm{init}} = 0.1 $, x O init = 0.1 $ x_{\mathrm{O}}^{\mathrm{init}} = 0.1 $, and x N init = 0.1 $ x_{\mathrm{N}}^{\mathrm{init}} = 0.1 $. They have already evolved to the values at the starting point of this plot. The reaction equilibrium is reached after τeq ≈ 2 × 1010 s as indicated as pink shaded area. We fix Te = const = 10 500 K during the simulation.

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