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Fig. 1

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Schematic depicting the setup of the volatile exchange during initialization (t=0) and run time. For initialization, a surface temperature of 4000 K and a completely molten magma ocean was assumed, where the dissolved volatiles are in balance with the outgassed volatile content, set by the volatile melt fraction, Fi. As the magma ocean solidifies, part of the volatile budget is deposited in the solid mantle. Furthermore, atmospheric escape can remove H2O. These two sink terms thus reduce the amount of a volatile available in the fully coupled MOA system, Mimoa$M_i^{moa{\rm{}}}$. The full overview of all included processes, including radiogenic heating, is shown in Barth et al. (2021, Fig. 1).

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