Fig. 1

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Distribution of matched cases in the entire case range is shown. Matched cases (i.e. red circles) represent the escape scenarios that can produce present Venusian atmospheric 20Ne/22Ne, 36Ar/38Ar and 20Ne/36Ar − 11.8 ± 0.7, 5.5 ± 0.6, and 0.25 ± 0.1, respectively (von Zahn et al. 1983; Donahue & Pollack 1983). Conversely, ‘unmatched cases’ do not satisfy all three isotopic ratios simultaneously. The X-axis represents the initial nebular hydrogen content in the Venusian atmosphere and the Y -axis represents the initial H2O content in the atmosphere. The horizontal dashed line represents an initial H2O inventory of 1.05 × 104 moles/cm2 and CO2 inventory of 2.3 × 103 moles/cm2 (about 90 bar of CO2 on present Venus). Cases above the line assume higher initial CO2 , while those below assume lower initial CO2 . The vertical dashed line represents an initial H2 content of 210 moles cm−2 (equal to 0.00004 wt%). For cases with initial nebular-source H2 below 210 moles cm−2, we coupled the radiactive-convective atmosphere model to the escape model and updated the escape height (where escape flux works) at each time step, assuming an initial 20Ne/36Ar ratio of 0.33 (i.e. a strongly fractionated value compared to the solar value). For cases with initial nebular-source H2 above 210 moles cm−2, our calculation applied only the escape model, keeping r0 fixed over time and assuming an initial 20Ne/36Ar ratio of 44.7 (i.e. the solar value).
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