Fig. 5

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Rate coefficients of various reactions, as indicated above each panel, as a function of temperature. The filled red, orange, and green circles indicate simulated rate coefficients based on the H3+ + D2, D2H+ + H2, and D3+ + H2 systems, respectively. The error bars are defined as in Fig. B.1. The values for the H3+ + D2 reaction are sums over the two product branches, that is, reactions 2 and 3 as given in Table3. The rate coefficients of the H2D+ + H2 → H3+ + HD, D2H+ + H2 → H2D+ + HD, and D3+ + H2 → D2H+ + HD reactions are both constrained by the D2H+ + H2 and the D3+ + H2 experimental systems and hence appear in two colors (D2H+ + H2 in orange; D3+ + H2 in green); the data have been offset by 3 K for better visibility of the error bars. The solid black lines indicate the experimentally deduced rate coefficients; these data are missing for the H2D+ + H2 → H3+ + HD reaction because they could not be determined experimentally. The dashed magenta lines show the rate coefficient values as derived from the Hugo et al. (2009) data (see also Table 3).
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