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Fig. B.2

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Experimental CP spectrum in the 107 GHz region where the NKa,KcNKa,Kc=50,540,4$\[N_{K_a^{\prime}, K_c^{\prime}}^{\prime}-N_{K_a^{\prime \prime}, K_c^{\prime \prime}}^{\prime \prime}=5_{0,5}-4_{0,4}\]$ a-type transition of H2NCO lies, and comparison with a simulation obtained with PGOPHER using the final set of spectroscopic parameters (see Table 1), a 300 K temperature, and a Gaussian profile with a full width at half maximum of 1 MHz.

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