Open Access
Table 1
Initial set of reactions proposed in this research.
| R/id | Reaction mechanisms (a-NH2CN) | R/id | Reaction mechanisms (b-HNCNH) |
|---|---|---|---|
| Ra1 | HNCNH → NH2 CN | Rb1 | NH2CN→HNCNH |
| Ra2 | 3CH2 +N2 → NH2 CN | Rb2 | 3 CH2 + N2 → HNCNH |
| Ra3 | 3CH2 +N2 H+ → NH2 CN + H+ | Rb3 | 3 CH2 + N2 H+ → HNCNH + H+ |
| Ra4 |  |
Rb4 |  |
| Ra5 | ·CN+·NH2 →NH2CN | Rb5 | ·CN+·NH2 →HNCNH |
| Ra6 | ·CN+NH3 →NH2CN+·H | Rb6 | ·CN+NH3 →HNCNH+·H |
| Ra7 | 1HNC+3NH→NH2CN | Rb7 | 1 HNC +3 NH → HNCNH |
| Ra8 | 1HNC+·NH2 → NH2CN+·H | Rb8 | 1 HNC+·NH2 → HNCNH+·H |
| Ra9 | 1HNC+NH3 → NH2CN+H2 | Rb9 | 1 HNC+NH3 → HNCNH+H2 |
| Ra10 | HCN+3NH→NH2CN | Rb10 | HCN+3NH→HNCNH |
| Ra11 | HCN+ N2H+ → NH2CN+ ·N+ | Rb11 | HCN+ N2H+ → HNCNH+·N+ |
| Ra12 | HCN+·NH2 →NH2CN+·H | Rb12 | HCN+·NH2 →HNCNH+·H |
| Ra13 | HCN+NH3 →NH2CN+H2 | Rb13 | HCN+NH3 →HNCNH+H2 |
| Ra14 | CH4 + N2H+ → NH2CN+ H3+ | Rb14 | CH4 + N2H+ → HNCNH + H3+ |
| Ra15 | H2CO + 1N2O → NH2CN + 3O2 | Rb15 | H2CO +1 N2O → HNCNH+3O2 |
| Ra16 | ·H2NC + ·N(2D) → NH2 CN | Rb16 | ·H2NC+·N(2D)→HNCNH |
| Ra17 | ·H2NC +·3NH→ NH2CN+·H | Rb17 | ·H2NC+3NH→HNCNH+·H |
| Ra18 | ·H2NC+·NH2 →NH2CN+H2 | Rb18 | ·H2NC+·NH2 →HNCNH+H2 |
| Ra19 | ·H2 NC +1 N2 O → NH2 CN + ·NO | Rb19 | ·H2NC+1N2O→HNCNH+·NO |
| Ra20 | ·H2NC +HCN→ NH2CN+·CH | Rb20 | ·H2NC+HCN→HNCNH+·CH |
| Ra21 | ·H2NC+HOCN→ NH2CN+·COH | Rb21 | ·H2NC+HOCN→HNCNH+·COH |
| Ra22 | ·H2 CN +1 N2 O → NH2 CN + ·NO | Rb22 | ·H2CN+1N2O→HNCNH+·NO |
| Ra23 | HCNO +·NH2 → NH2CN+2·OH | Rb23 | HCNO +·NH2 → HNCNH+2·OH |
| Ra24 | HCNO +NH3 → NH2CN+H2O | Rb24 | HCNO +NH3 → HNCNH+H2O |
| Ra25 | HNCO + NH3 → NH2CN+ H2O | Rb25 | HNCO +NH3 → HNCNH+H2O |
| Ra26 | HOCN + NH3 → NH2CN + H2O | Rb26 | HOCN+NH3 →HNCNH+H2O |
| Ra27 | CNCN+H2O→NH2CN+1CO | Rb27 | CNCN+H2O→HNCNH+1CO |
| Ra28 | C2H4+N2→NH2CN+3CH2 | Rb28 | C2H4+N2→HNCNH+3CH2 |
| Ra29 | H2CNH1 +HCN→NH2CN+3CH2 | Rb29 | H2CNH1 +HCN→HNCNH+3CH2 |
| Ra30 | H2CNH1 + ·NO→ NH2CN+·2OH | Rb30 | H2 CNH1 + ·NO→ HNCNH+ ·2OH |
| Ra31 | HCNH+ +NH3→ NH2CN+H3+ | Rb31 | HCNH+ +NH3→ HNCNH+H3+ |
| Ra32 | HCNH+ + HNO→ NH2CN+ OH+ | Rb32 | HCNH+ +HNO→ HNCNH+OH+ |
| Ra33 | HCNH+ +1 N2O→ NH2CN+NO+ | Rb33 | HCNH+ +1 N2O→ HNCNH+NO+ |
| Ra34 | ·HNCN+·H→NH2CN | Rb34 | ·HNCN+·H→HNCNH |
| Ra35 | ·HNCN+H2 →NH2CN+·H | Rb35 | ·HNCN+H2 →HNCNH+·H |
| Ra36 | ·HNCN+3NH→ NH2CN+·N | Rb36 | ·HNCN+3NH→ HNCNH+·N |
| Ra37 | ·HNCN+·NH2 →NH2CN+3NH | Rb37 | ·HNCN+·NH2 →HNCNH+3NH |
| Ra38 | ·HNCN+NH3 →HN2CN+·NH2 | Rb38 | ·HNCN+NH3 →HNCNH+·NH2 |
| Ra39 | ·HNCN+3CH2 →NH2CN+·CH | Rb39 | ·HNCN+3CH2 →HNCNH+·CH |
| Ra40 | ·HNCN+·CH3 →NH2CN+3CH2 | Rb40 | ·HNCN+·CH3 →HNCNH+3CH2 |
| Ra41 | ·HNCN+H2O →NH2CN+·2OH | Rb41 | ·HNCN+H2O→HNCNH+·OH |
| Ra42 | ·HNCN+1HNC→NH2CN+·CN | Rb42 | ·HNCN+1HCN→HNCNH+·CN |
| Ra43 | ·HNCN+HCN→NH2CN+·CN | Rb43 | ·HNCN+HCN→HNCNH+·CN |
| Ra44 | ·HNCN+HNCO→NH2CN+·NCO | Rb44 | ·HNCN+HNCO→HNCNH+·NCO |
| Ra45 | ·HNCN+HOCN→NH2CN+·NCO, | Rb45 | ·HNCN+ HOCN → HNCNH+·NCO |
| Ra46 | ·HNCN+ HCNO → NH2CN+·CNO | Rb46 | ·HNCN+HCNO→HNCNH+·CNO |
| Ra47 | ·HNCN+·HNCN→NH2CN+·NCN | Rb47 | ·HNCN+·HNCN→HNCNH+·NCN |
| Ra48 | NH2CHO+·N→NH2CN+·2OH | Rb48 | NH2CHO+·N→HNCNH+·2OH |
| Ra49 | NH2CHO+N2 → NH2CN+HNO | Rb49 | NH2CHO+N2 →HNCNH+HNO |
| Ra50 | NH2 CHO + 3NH → NH2CN+ H2O | Rb50 | NH2CHO +3NH → HNCNH+H2O |
| Ra51 | NH2CHO+NO→NH2CN+·HO2 | Rb51 | NH2CHO+NO →HNCNH+·HO2 |
| Ra52 | NH2CHO +·CN→ NH2CN+·HCO | Rb52 | NH2 CHO + ·CN → HNCNH+ ·HCO |
| Ra53 | NH2CHO+HNO→NH2CN+H2O2 | Rb53 | NH2CHO+HNO→HNCNH+H2O2 |
| Ra54 | NH2CHO+NH2 → NH2CN+·2OH+H2 | Rb54 | NH2CHO+NH2 →HNCNH+·2OH+H2 |
| Ra55 | NH2CHO+N2H→NH2CN+NO+H2 | Rb55 | NH2CHO+N2H→HNCNH+NO+H2 |
| Ra56 | NH2CHO+1 HNC → NH2CN+trans-1HOCH | Rb56 | NH2 CHO +1 HNC → HNCNH+1 H2CO |
| Ra57 | NH2CHO+HCN→ NH2CN+trans 1HOCH | Rb57 | NH2 CHO + HCN → HNCNH+1 H2CO |
| Ra58 | NH2CHO+1N2O→NH2CN+trans-HONO | Rb58 | NH2CHO+1N2O→HNCNH+trans-HONO |
| Ra59 | NH2CHO+1 N2O → NH2CN+cis-HONO | Rb59 | NH2 CHO +1 N2O → HNCNH+ cis-HONO |
| Ra60 | CH3NH2 +·CN→ NH2CN+·CH3 | Rb60 | CH3NH2 +·CN→ HNCNH+·CH3 |
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