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Table 6
Crossover temperatures (Tc in K) and reaction rate-constants k(Tmin, in s−1) at the lowest temperature achieved in our calculations (Tmin in K), for the exothermic reactions starting from C2H6.
| Reaction | Tc(K) | Tmin (K) | k(Tmin) (s−1) |
|---|---|---|---|
| C2H6 + H → C2H5 + H2 | 312 | 65 | 5.6 × 100 |
| C2H6 + OH → C2H5 + H2O | 231 | 25 | 1.5 × 103 |
| C2H6 + NH2 → C2H5 + NH3(a) | 412 | 20 | 6.3 × 100 |
| C2H6 + CH3 → C2H5 + CH4(a) | 402 | 20 | 2.3 × 10−4 |
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