Methoxymethanol formation starting from CO hydrogenation

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Table 1

Experiments performed in this study.

	Reactants	T (K)	H dep. (ML)	CO/H₂CO/MF dep. (ML)	MM:MeOH
Exp. 1	¹³CO + H	10	50.0	2.7	0.005
Exp. 2	C¹⁸O + H	10	50.0	2.1	0.005
Exp. 3	¹²CO + H	10	50.0	1.5	0.004
Exp. 4	+ H	10	50.0	1.7	0.005
Exp. 5	+ H	10	50.0	2.0	0.005
Exp. 6	+ H	25	50.0	2.6	–
Exp. 7	¹³CO + H	25	50.0	2.0	–
Exp. 8	MF + H	10	52.0	36.0	–

Notes. The amount of CO/H₂CO/MF deposited is obtained from the IR data, while the amount of H deposited is from a separate calibration. After deposition, the ices are heated up at a ramp rate of5 K min⁻¹ to do a TPD. The resulting MeOH:MM ratio in the reaction product is shown.

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