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Fig. A.1

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Distribution plot of quantum numbers of rotational transitions measured and fitted for the ground-state doublet of glycinamide. Symbol diameter is proportional to the value of |fobs-calc|∕σ where fobs-calc is the residual of fit for a given line and σ is its measurement uncertainty. Red colour identifies outliers with |fobs-calc|∕σ > 3. The few outliers are all for confidently assigned transitions and may be due either to blends with unassigned lines or incompletely treated perturbation contributions.

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