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Table 2

Reaction coefficients of the reactions used in this paper.

Reaction α β γ k(100 K) k(150 K) Units Ref. NW W
ζcr 1(−17) 0 0 1(−17) 1(−17) s-1
k2 2.1(−9) 0 0 2.1(−9) 2.1(−9) cm3 s-1 (a)
k3 2.3(−8) − 0.5 0 4.1(−8) 3.4(−8) cm3 s-1 (b)
k4 1.4(−9) − 0.1 − 3.4 1.6(−9) 1.5(−9) cm3 s-1 (c)
HCO+ + e-→ CO + H 2.4(−7) − 0.7 0 5.1(−7) 3.9(−7) cm3 s-1 (d)
HCO+ + H2O → CO + H3O+ 2.5(−9) − 0.5 0 4.3(−9) 3.5(−9) cm3 s-1 (e)
k7 H3O+ + e-→ H2O + H 7.1(−8) − 0.5 0 1.2(−7) 1.0(−7) cm3 s-1 (f)
k8 5.9(−9) − 0.5 0 1.0(−8) 8.3(−9) cm3 s-1 (g, h)
kf H2O → H2O (ice) 0.5 0 s-1 (i)
kd H2O (ice) → H2O 2.8(12) 0 5.8(3) 2.4(−13) 5.4(−5) s-1 (i)

Notes. The last two columns indicate in which chemical networks the reactions are used. a(b) represents a × 10b. NW is the chemical network without water, whereas W includes water. All reactions are given in the form , where the values of α, β, and γ for k2, k3, k4, , , k7, and k8 are taken from the rate12 UMIST database (McElroy et al. 2013) and kd uses Tdust instead of Tgas.

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