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Table B.7.
Peak position and FWHM of the acetone CH3 asymmetric deformation mode for pure acetone and mixtures with acetone ratio 1:20 and for temperatures ranging from 15 K to 140 K. See also Figs. A.9 and A.10.
| Mixture | Temperature | Peak position |
FWHM |
||
|---|---|---|---|---|---|
| (K) | (cm−1) | (μm) | (cm−1) | (μm) | |
| CH3COCH3 | 1417.9 | 7.0527 | 40.9 | 0.199* | |
| 1441.0 | 6.9394 | – | – | ||
| CH3COCH3:CO | 1416.9 | 7.0575 | 9.5 | 0.0475 | |
| 1435.0 | 6.9685 | 17.3 | 0.0885* | ||
| 1443.7 | 6.9267 | – | – | ||
| CH3COCH3:CO2 | 15 | 1420.3 | 7.0407 | 9.5 | 0.0469 |
| 1445.4 | 6.9186 | – | – | ||
| CH3COCH3:H2O | 1422.0 | 7.0323 | 14.8 | 0.0730 | |
| 1445.3 | 6.9192 | – | – | ||
| CH3COCH3:H2O :CO2 | 1422.5 | 7.0299 | 12.7 | 0.0624 | |
| 1444.4 | 6.9232 | – | – | ||
| CH3COCH3:H2O:CH4 | 1422.7 | 12.1 | |||
| 1443.0 | |||||
| CH3COCH3 | 1417.9 | 7.0527 | 40.9 | 0.199* | |
| 1441.3 | 6.9382 | – | – | ||
| CH3COCH3:CO | 1417.4 | 7.0551 | 10.6 | 0.0527 | |
| 1436.7 | 6.9604 | 17.1 | 0.0912 | ||
| CH3COCH3:CO2 | 30 | 1420.6 | 7.0395 | 11.2 | 0.0556 |
| 1444.9 | 6.9209 | – | – | ||
| CH3COCH3:H2O | 1421.8 | 7.0335 | 14.5 | 0.0716 | |
| 1442.0 | 6.9348 | – | – | ||
| CH3COCH3:H2O :CO2 | 1422.2 | 7.0311 | 12.9 | 0.0635 | |
| 1444.4 | 6.9232 | – | – | ||
| CH3COCH3:H2O:CH4 | 1422.7 | 7.0289 | 12.0 | ||
| 1443.2 | 6.929 | ||||
| CH3COCH3 | 1418.1 | 7.0515 | 39.6 | 0.193* | |
| 1441.0 | 6.9394 | – | – | ||
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | 1420.3 | 7.0407 | 37.5 | 0.183* | |
| 1439.4 | 6.9475 | – | – | ||
| CH3COCH3:H2O | 70 | 1421.5 | 7.0347 | 14.0 | 0.0693 |
| 1439.9 | 6.9450 | – | – | ||
| CH3COCH3:H2O :CO2 | 1422.2 | 7.0311 | – | – | |
| 1442.3 | 6.9336 | 12.2 | 0.0601 | ||
| CH3COCH3:H2O:CH4 | 1423.2 | 7.0264 | 13.8 | ||
| 1441.2 | 6.9387 | ||||
| CH3COCH3 | 1418.1 | 7.0515 | 38.7 | 0.189* | |
| 1440.8 | 6.9406 | – | – | ||
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | 1419.8 | 7.0431 | 35.5 | 0.173* | |
| 1439.6 | 6.9464 | – | – | ||
| CH3COCH3:H2O | 90 | 1421.5 | 7.0347 | 13.9 | 0.0685 |
| 1439.5 | 6.9467 | – | – | ||
| CH3COCH3:H2O :CO2 | 1422.2 | 7.0311 | 12.2 | 0.0602 | |
| 1441.0 | 6.9359 | – | – | ||
| CH3COCH3:H2O:CH4 | 1423.4 | 7.0254 | 13.9 | ||
| 1443.0 | 6.93 | ||||
| CH3COCH3 | 1401.8 | 7.1339 | – | – | |
| 1417.4 | 7.0551 | 10.8 | 0.0538 | ||
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | 1417.4 | 7.0551 | 13.7 | 0.0682 | |
| 1437.2 | 6.9580 | – | – | ||
| CH3COCH3:H2O | 100 | 1421.8 | 7.0335 | 14.1 | 0.0695 |
| CH3COCH3:H2O :CO2 | 1422.0 | 7.0323 | 14.9 | 0.0735 | |
| 1439.6 | 6.9464 | – | – | ||
| CH3COCH3:H2O:CH4 | 1423.4 | 7.0254 | 14.0 | ||
| 1441.0 | 6.9396 | ||||
| CH3COCH3 | 1402.2 | 7.1315 | – | – | |
| 1417.7 | 7.0539 | 11.5 | 0.0569 | ||
| 1438.6 | 6.9510 | – | – | ||
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | – | – | – | – | |
| CH3COCH3:H2O | 110 | 1421.8 | 7.0335 | 14.7 | 0.0727 |
| CH3COCH3:H2O :CO2 | 1422.0 | 7.0323 | – | – | |
| 1439.6 | 6.9464 | 14.8 | 0.0731 | ||
| CH3COCH3:H2O:CH4 | 1423.4 | 7.0254 | 14.5 | ||
| 1441.0 | 6.9396 | ||||
| CH3COCH3 | 1402.5 | 7.1302 | – | – | |
| 1417.9 | 7.0527 | 12.1 | 0.0599 | ||
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | – | – | – | – | |
| CH3COCH3:H2O | 120 | 1421.8 | 7.0335 | 14.5 | 0.0715 |
| CH3COCH3:H2O :CO2 | 1422.0 | 7.0323 | 15.2 | 0.0752 | |
| 143.7 | 6.9557 | – | – | ||
| CH3COCH3:H2O:CH4 | 1423.4 | 7.0254 | 14.1 | ||
| 1438.9 | 6.9498 | ||||
| CH3COCH3 | 1404.9 | 7.1180 | – | – | |
| 1417.7 | 7.0539 | 12.2 | 0.0607 | ||
| 1439.8 | 6.9452 | – | – | ||
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | – | – | – | – | |
| CH3COCH3:H2O | 140 | 1421.8 | 7.0335 | 16.4 | 0.0812 |
| CH3COCH3:H2O:CO2 | 1417.4 | 7.0551 | 27.1 | 0.133* | |
| 1437.5 | 6.9566 | – | – | ||
| CH3COCH3:H2O:CH4 | 1421.3 | 7.0358 | 29.5 | ||
| 1438.6 | 6.9512 | ||||
| CH3COCH3 | – | – | – | – | |
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | 160 | – | – | – | – |
| CH3COCH3:H2O | 1422.0 | 7.0323 | 25.2 | 0.124 | |
| CH3COCH3:H2O :CO2 | – | – | – | – | |
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