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Table B.6.
Peak position and FWHM of the acetone CO-stretch mode for pure acetone and mixtures with acetone ratio 1:20 and for temperatures ranging from 15 K to 140 K. See also Figs. A.7 and A.8.
| Mixture | Temperature | Peak position |
FWHM |
||
|---|---|---|---|---|---|
| (K) | (cm−1) | (μm) | (cm−1) | (μm) | |
| CH3COCH3 | 1710.3 | 5.8469 | 18.7 | 0.0640 | |
| CH3COCH3:CO | 1717.3 | 5.8231 | 6.8 | 0.0232 | |
| CH3COCH3:CO2 | 1710.6 | 5.8461 | 11.5 | 0.0392 | |
| CH3COCH3:H2O | 1696.8 | 5.8934 | 23.5 | 0.0813 | |
| CH3COCH3:CH3OH | 15 | 1699.5 | 5.8842 | – | – |
| 1708.9 | 5.8518 | 21.2 | 0.0731* | ||
| CH3COCH3:H2O:CO2 | 1695.6 | 5.8976 | 21.4 | 0.0745 | |
| CH3COCH3:H2O:CH4 | 1697.5 | 5.9810 | 17.1 | ||
| CH3COCH3:CH3OH:CO | 1700.2 | 5.8817 | 20.4 | 0.0704* | |
| 1711.1 | 5.8444 | – | – | ||
| CH3COCH3 | 1709.8 | 5.8485 | 18.7 | 0.0640 | |
| CH3COCH3:CO | 1717.3 | 5.8231 | 9.7 | 0.0330 | |
| CH3COCH3:CO2 | 1710.6 | 5.8461 | 11.3 | 0.0384 | |
| CH3COCH3:H2O | 1696.8 | 5.8934 | 23.5 | 0.0816 | |
| CH3COCH3:CH3OH | 30 | 1699.0 | 5.8859 | – | – |
| 1709.6 | 5.8494 | 21.5 | 0.0742* | ||
| CH3COCH3:H2O:CO2 | 1695.8 | 5.8968 | 21.0 | 0.0728 | |
| CH3COCH3:H2O:CH4 | 1697.5 | 5.8910 | 16.9 | ||
| CH3COCH3:CH3OH:CO | 1699.9 | 5.8825 | – | – | |
| 1711.5 | 5.8428 | 12.0 | 0.0416 | ||
| CH3COCH3 | 1708.9 | 5.8518 | 18.3 | 0.0628 | |
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | 1716.6 | 5.8255 | 11.3 | 0.0384 | |
| CH3COCH3:H2O | 1696.8 | 5.8934 | 24.6 | 0.0853* | |
| CH3COCH3:CH3OH | 70 | 1698.5 | 5.8876 | – | |
| 1710.3 | 5.8469 | 20.0 | 0.0680* | ||
| CH3COCH3:H2O:CO2 | 1695.1 | 5.8993 | 19.7 | 0.0684 | |
| CH3COCH3:H2O:CH4 | 1695.4 | 5.8983 | 20.7 | ||
| CH3COCH3:CH3OH:CO | 1698.3 | 5.8884 | – | – | |
| 1710.8 | 5.8452 | 10.6 | 0.0362 | ||
| CH3COCH3 | 1708.6 | 5.8527 | 17.8 | 0.0611 | |
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | 1716.3 | 5.8264 | 12.4 | 0.0422 | |
| CH3COCH3:H2O | 1696.8 | 5.8934 | 25.7 | 0.0891 | |
| CH3COCH3:CH3OH | 90 | 1698.0 | 5.8892 | – | – |
| 1710.6 | 5.8461 | 9.0 | 0.0308 | ||
| CH3COCH3:H2O:CO2 | 1695.1 | 5.8993 | 20.0 | 0.0697 | |
| CH3COCH3:H2O:CH4 | 1695.1 | 5.8994 | 21.0 | ||
| CH3COCH3:CH3OH:CO | 1697.5 | 5.8909 | – | – | |
| 1710.1 | 5.8477 | 10.7 | 0.0367 | ||
| CH3COCH3 | 1697.5 | 5.8909 | – | – | |
| 1706.7 | 5.8593 | – | – | ||
| 1713.9 | 5.8346 | 13.5 | 0.0463* | ||
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | 100 | 1706.9 | 5.8585 | 11.4 | 0.0391* |
| 1713.7 | 5.8354 | – | – | ||
| CH3COCH3:H2O | 1696.8 | 5.8934 | 25.8 | 0.0895* | |
| CH3COCH3:CH3OH | 1698.0 | 5.8892 | – | – | |
| 1710.6 | 5.8461 | 9.0 | 0.0306* | ||
| CH3COCH3:H2O:CO2 | 1700.9 | 5.8792 | 22.4 | 0.0775 | |
| CH3COCH3:H2O:CH4 | 1695.4 | 5.8983 | 21.6 | ||
| CH3COCH3:CH3OH:CO | 1698.0 | 5.8892 | – | – | |
| 1710.3 | 5.8469 | 10.7 | 0.0367 | ||
| CH3COCH3 | 1697.8 | 5.8901 | – | – | |
| 1706.9 | 5.8585 | – | – | ||
| 1713.9 | 5.8346 | 13.5 | 0.0463* | ||
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | – | – | – | – | |
| CH3COCH3:H2O | 110 | 1699.0 | 5.8859 | 25.9 | 0.0898 |
| CH3COCH3:CH3OH | 1699.2 | 5.8851 | – | – | |
| 1710.6 | 5.8461 | 9.8 | 0.0335 | ||
| CH3COCH3:H2O:CO2 | 1701.4 | 5.8775 | 22.6 | 0.0783 | |
| CH3COCH3:H2O:CH4 | 1695.1 | 5.8994 | 22.1 | ||
| CH3COCH3:CH3OH:CO | 1698.3 | 5.8884 | – | – | |
| 1707.9 | 5.8551 | 12.3 | 0.0420* | ||
| 1714.2 | 5.8337 | – | – | ||
| CH3COCH3 | 1698.0 | 5.8892 | – | – | |
| 1706.9 | 5.8585 | – | – | ||
| 1713.9 | 5.8346 | 13.5 | 0.0460* | ||
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | – | – | – | – | |
| CH3COCH3:H2O | 1703.3 | 5.8709 | 25.9 | 0.0895 | |
| CH3COCH3:CH3OH | 120 | 1707.4 | 5.8568 | 19.5 | 0.0669 |
| CH3COCH3:H2O:CO2 | 1703.6 | 5.8701 | 21.9 | 0.0759 | |
| CH3COCH3:H2O:CH4 | 1697.8 | 5.8900 | 23.2 | ||
| CH3COCH3:CH3OH:CO | 1698.0 | 5.8892 | – | – | |
| 1707.9 | 5.8551 | 11.5 | 0.0393* | ||
| 1714.4 | 5.8329 | – | – | ||
| CH3COCH3 | 1698.0 | 5.8892 | – | – | |
| 1706.9 | 5.8585 | – | – | ||
| 1713.7 | 5.8354 | 13.3 | 0.0453* | ||
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | – | – | – | – | |
| CH3COCH3:H2O | 140 | 1703.3 | 5.8709 | 25.4 | 0.0880 |
| CH3COCH3:CH3OH | 1697.8 | 5.8901 | – | – | |
| 1708.1 | 5.8543 | 5.4 | 0.0187 | ||
| 1714.2 | 5.8337 | – | – | ||
| CH3COCH3:H2O:CO2 | 1705.7 | 5.8626 | 32.1 | 0.110 | |
| CH3COCH3:H2O:CH4 | 1708.6 | 5.8527 | 30.3 | ||
| CH3COCH3:CH3OH:CO | – | – | – | – | |
| CH3COCH3 | – | – | – | – | |
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | – | – | – | – | |
| CH3COCH3:H2O | 160 | 1703.1 | 5.8717 | 38.8 | 0.134 |
| CH3COCH3:CH3OH | – | – | – | – | |
| CH3COCH3:H2O:CO2 | – | – | – | – | |
| CH3COCH3:H2O:CH4 | – | – | – | – | |
| CH3COCH3:CH3OH:CO | – | – | – | – | |
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