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Table B.5.
Peak position and FWHM of the acetone CO in-plane deformation mode for pure acetone and mixtures with acetone ratio 1:5 and for temperatures ranging from 15 K to 140 K. See also Figs. A.5 and A.6.
| Mixture | Temperature | Peak position |
FWHM |
||
|---|---|---|---|---|---|
| (K) | (cm−1) | (μm) | (cm−1) | (μm) | |
| CH3COCH3 | 532.7 | 18.771 | 7.6 | 0.266 | |
| CH3COCH3:CO | 532.0 | 18.796 | 4.4 | 0.155 | |
| CH3COCH3:CO2 | 535.6 | 18.669 | 6.8 | 0.236 | |
| CH3COCH3:H2O | 15 | 547.0 | 18.283 | 17.5 | 0.588 |
| CH3COCH3:CH3OH | 532.5 | 18.779 | 6.4 | 0.224 | |
| CH3COCH3:H2O:CO2 | 544.8 | 18.356 | 16.1 | 0.539 | |
| CH3COCH3:H2O:CH4 | 544.1 | 18.38 | 11.5 | ||
| CH3COCH3:CH3OH:CO | 532.0 | 18.796 | 4.9 | 0.174 | |
| CH3COCH3 | 532.7 | 18.771 | 7.5 | 0.264 | |
| CH3COCH3:CO | 532.5 | 18.779 | 4.7 | 0.165 | |
| CH3COCH3:CO2 | 535.6 | 18.669 | 6.5 | 0.226 | |
| CH3COCH3:H2O | 542.6 | 18.429 | 15.8 | 0.533 | |
| CH3COCH3:CH3OH | 30 | 532.0 | 18.796 | 6.2 | 0.219 |
| CH3COCH3:H2O:CO2 | 544.6 | 18.364 | 16.0 | 0.536 | |
| CH3COCH3:H2O:CH4 | 545.3 | 18.78 | 11.6 | ||
| CH3COCH3:CH3OH:CO | 532.7 | 18.771 | 5.2 | 0.184 | |
| CH3COCH3 | 532.5 | 18.779 | 7.1 | 0.249 | |
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | 535.1 | 18.686 | 6.4 | 0.228 | |
| CH3COCH3:H2O | 542.6 | 18.429 | 15.8 | 0.533 | |
| CH3COCH3:CH3OH | 70 | 532.3 | 18.788 | 5.9 | 0.209 |
| CH3COCH3:H2O:CO2 | 544.8 | 18.356 | 12.2 | 0.411 | |
| CH3COCH3:H2O:CH4 | 542.1 | 18.45 | 10.7 | ||
| CH3COCH3:CH3OH:CO | 532.5 | 18.779 | 5.5 | 0.192 | |
| CH3COCH3 | 532.3 | 18.788 | 6.8 | 0.240 | |
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | 533.7 | 18.737 | 6.0 | 0.213 | |
| CH3COCH3:H2O | 542.1 | 18.445 | 12.5 | 0.422 | |
| CH3COCH3:CH3OH | 90 | 531.8 | 18.805 | 5.2 | 0.185 |
| CH3COCH3:H2O:CO2 | 541.9 | 18.454 | 10.3 | 0.347 | |
| CH3COCH3:H2O:CH4 | 542.1 | 18.45 | 10.4 | ||
| CH3COCH3:CH3OH:CO | 531.5 | 18.813 | 5.6 | 0.198 | |
| CH3COCH3 | 532.7 | 18.771 | 4.0 | 0.141 | |
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | 532.7 | 18.771 | 6.2 | 0.219 | |
| CH3COCH3:H2O | 542.1 | 18.445 | 11.6 | 0.392 | |
| CH3COCH3:CH3OH | 100 | 531.8 | 18.805 | 5.1 | 0.181 |
| CH3COCH3:H2O:CO2 | 543.3 | 18.404 | 8.5 | 0.289 | |
| CH3COCH3:H2O:CH4 | 542.1 | 18.45 | 10.5 | ||
| CH3COCH3:CH3OH:CO | 532.5 | 18.779 | 5.5 | 0.194 | |
| CH3COCH3 | 532.5 | 18.779 | 4.1 | 0.141 | |
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | – | – | – | – | |
| CH3COCH3:H2O | 110 | 542.1 | 18.445 | 9.7 | 0.330 |
| CH3COCH3:CH3OH | 531.5 | 18.813 | 4.8 | 0.171 | |
| CH3COCH3:H2O:CO2 | 541.9 | 18.454 | 7.5 | 0.254 | |
| CH3COCH3:H2O:CH4 | 542.4 | 18.44 | 10.1 | ||
| CH3COCH3:CH3OH:CO | 533.0 | 18.762 | 3.3 | 0.114 | |
| CH3COCH3 | 532.3 | 18.788 | 4.1 | 0.143 | |
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | – | – | – | – | |
| CH3COCH3:H2O | 120 | 542.1 | 18.445 | 8.7 | 0.296 |
| CH3COCH3:CH3OH | 533.9 | 18.728 | 3.7 | 0.129 | |
| CH3COCH3:H2O:CO2 | 541.9 | 18.454 | 5.6 | 0.189 | |
| CH3COCH3:H2O:CH4 | 531.5 | 18.81 | 7.0 | ||
| CH3COCH3:CH3OH:CO | 533.0 | 18.762 | 3.1 | 0.110 | |
| CH3COCH3 | 531.5 | 18.813 | 4.2 | 0.147 | |
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | – | – | – | – | |
| CH3COCH3:H2O | 541.9 | 18.454 | – | – | |
| 140 | 529.6 | 18.882 | – | – | |
| CH3COCH3:CH3OH | 533.0 | 18.762 | 2.7 | 0.097 | |
| CH3COCH3:H2O:CO2 | – | – | – | – | |
| CH3COCH3:H2O:CH4 | 531.1 | 18.83 | 6.3 | ||
| CH3COCH3:CH3OH:CO | 532.7 | 18.77 | 3.4 | 0.129 | |
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