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Table B.3.
Peak position and FWHM of the acetone CH3 symmetric deformation mode for pure acetone and mixtures with acetone ratio 1:5 and for temperatures ranging from 15 K to 140 K. See also Figs. A.3 and A.4
| Mixture | Temperature | Peak position |
FWHM |
||
|---|---|---|---|---|---|
| (K) | (cm−1) | (μm) | (cm−1) | (μm) | |
| CH3COCH3 | 1363.4 | 7.3345 | 19.2 | 0.0640 | |
| CH3COCH3:CO | 1354.0 | 7.3854 | 7.7 | 0.0420 | |
| 1364.6 | 7.3280 | 6.2 | 0.0330 | ||
| CH3COCH3:CO2 | 1356.4 | 7.3723 | – | – | |
| 1367.0 | 7.3151 | 7.8 | 0.0420 | ||
| CH3COCH3:H2O | 15 | 1356.9 | 7.3696 | – | – |
| 1370.7 | 7.2958 | 23.5 | 0.127* | ||
| CH3COCH3:CH3OH | 1366.6 | 7.3176 | 16.1 | 0.0861 | |
| CH3COCH3:H2O:CO2 | 1358.1 | 7.3631 | – | – | |
| 1370.9 | 7.2945 | 12.6 | 0.0640 | ||
| CH3COCH3:H2O:CH4 | 1358.8 | 7.3594 | 10.6 | ||
| 1371.9 | 7.2892 | 12.8 | |||
| CH3COCH3:CH3OH:CO | 1355.2 | 7.3788 | – | – | |
| 1367.5 | 7.3125 | 15.1 | 0.0810 | ||
| CH3COCH3 | 1363.2 | 7.3358 | 19.7 | 0.106 | |
| CH3COCH3:CO | 1353.1 | 7.3907 | – | – | |
| 1364.6 | 7.3280 | 7.5 | 0.0404 | ||
| CH3COCH3:CO2 | 1356.2 | 7.3736 | – | – | |
| 1367.0 | 7.3151 | 7.9 | 0.0424 | ||
| CH3COCH3:H2O | 30 | 1356.4 | 7.3723 | – | – |
| 1369.7 | 7.3009 | 23.6 | 0.127* | ||
| CH3COCH3:CH3OH | 1365.8 | 7.3215 | 15.9 | 0.0853 | |
| CH3COCH3:H2O:CO2 | 1358.1 | 7.3631 | – | – | |
| 1370.9 | 7.2945 | 12.5 | 0.0664 | ||
| CH3COCH3:H2O:CH4 | 1358.8 | 7.3594 | 10.6 | ||
| 1371.4 | 7.2918 | 12.5 | |||
| CH3COCH3:CH3OH:CO | 1355.0 | 7.3801 | – | – | |
| 1367.3 | 7.3138 | 14.9 | 0.0796 | ||
| CH3COCH3 | 1363.2 | 7.3358 | 20.8 | 0.112 | |
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | 1356.0 | 7.3749 | – | – | |
| 1366.6 | 7.3176 | 9.2 | 0.0491 | ||
| CH3COCH3:H2O | 70 | 1356.4 | 7.3723 | – | – |
| 1369.7 | 7.3009 | 23.6 | 0.127* | ||
| CH3COCH3:CH3OH | 1365.1 | 7.3254 | 15.4 | 0.0827 | |
| CH3COCH3:H2O:CO2 | 1357.9 | 7.3644 | – | – | |
| 1370.4 | 7.2970 | 12.8 | 0.0682 | ||
| CH3COCH3:H2O:CH4 | 1357.4 | 7.367 | 10.4 | ||
| 1370.4 | 7.2971 | 13.8 | |||
| CH3COCH3:CH3OH:CO | 1353.8 | 7.3867 | – | – | |
| 1364.4 | 7.3293 | 12.0 | 0.0642 | ||
| CH3COCH3 | 1363.2 | 7.3358 | 21.0 | 0.113 | |
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | 1364.9 | 7.3267 | 17.5 | 0.0944* | |
| CH3COCH3:H2O | 1356.4 | 7.3723 | – | – | |
| 1369.7 | 7.3009 | 23.6 | 0.127* | ||
| CH3COCH3:CH3OH | 90 | 1363.9 | 7.3319 | 12.7 | 0.0681 |
| CH3COCH3:H2O:CO2 | 1357.6 | 7.3657 | – | – | |
| 1370.2 | 7.2983 | 14.0 | 0.0746 | ||
| CH3COCH3:H2O:CH4 | 1357.4 | 7.367 | 10.4 | ||
| 1370.4 | 7.2971 | 14.3 | |||
| CH3COCH3:CH3OH:CO | 1353.7 | 7.3869 | – | – | |
| 1363.7 | 7.3332 | 12.2 | 0.0657 | ||
| CH3COCH3 | 1345.3 | 7.4330 | 7.7 | 0.0424* | |
| 1349.2 | 7.4118 | – | – | ||
| 1361.3 | 7.3462 | 8.8 | 0.0472 | ||
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | 1364.4 | 7.3293 | 17.9 | 0.0966* | |
| CH3COCH3:H2O | 1356.4 | 7.3723 | – | – | |
| 1369.7 | 7.3009 | 23.6 | 0.127* | ||
| CH3COCH3:CH3OH | 100 | 1363.7 | 7.3332 | 12.3 | 0.0662 |
| CH3COCH3:H2O:CO2 | 1356.9 | 7.3696 | – | – | |
| 1369.9 | 7.2996 | 22.4 | 0.120* | ||
| CH3COCH3:H2O:CH4 | 1357.4 | 7.367 | 10.3 | ||
| 1370.4 | 7.2971 | 14.5 | |||
| CH3COCH3:CH3OH:CO | 1364.1 | 7.3306 | 12.3 | 0.0661 | |
| CH3COCH3 | 1345.6 | 7.4317 | 7.5 | 0.0413* | |
| 1349.2 | 7.4118 | – | – | ||
| 1361.0 | 7.3475 | 8.7 | 0.0471 | ||
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | – | – | – | – | |
| CH3COCH3:H2O | 110 | 1356.4 | 7.3723 | – | – |
| 1369.7 | 7.3009 | 23.6 | 0.127* | ||
| CH3COCH3:CH3OH | 1363.4 | 7.3345 | 13.8 | 0.0745 | |
| CH3COCH3:H2O:CO2 | 1356.7 | 7.3710 | – | – | |
| 1369.7 | 7.3009 | 22.6 | 0.1215* | ||
| CH3COCH3:H2O:CH4 | 1357.4 | 7.367 | 10.2 | ||
| 1370.2 | 7.2982 | 14.6 | |||
| CH3COCH3:CH3OH:CO | 1344.1 | 7.4397 | – | – | |
| 1349.0 | 7.4131 | – | – | ||
| 1365.6 | 7.3228 | 8.7 | 0.047 | ||
| CH3COCH3 | 1346.1 | 7.4290 | 7.3 | 0.0404* | |
| 1349.4 | 7.4105 | – | – | ||
| 1360.8 | 7.3488 | 8.7 | 0.0470 | ||
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | – | – | – | – | |
| CH3COCH3:H2O | 1356.4 | 7.3723 | – | ||
| 1369.5 | 7.3022 | 23.7 | 0.127* | ||
| CH3COCH3:CH3OH | 120 | 1344.4 | 7.4384 | – | – |
| 1349.2 | 7.4118 | – | – | ||
| 1365.8 | 7.3215 | 10.2 | 0.0548 | ||
| CH3COCH3:H2O:CO2 | 1356.7 | 7.3710 | – | – | |
| 1369.2 | 7.3035 | 22.8 | 0.122* | ||
| CH3COCH3:H2O:CH4 | 1366.8 | 7.3163 | 21.3 | ||
| CH3COCH3:CH3OH:CO | 1344.1 | 7.4397 | – | – | |
| 1349.2 | 7.4118 | – | – | ||
| 1365.4 | 7.3241 | 8.8 | 0.0472 | ||
| CH3COCH3 | 1346.6 | 7.4264 | – | – | |
| 1350.9 | 7.4025 | – | – | ||
| 1361.7 | 7.3436 | 9.3 | 0.0499 | ||
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | – | – | – | – | |
| CH3COCH3:H2O | 1356.4 | 7.3723 | – | – | |
| 1367.8 | 7.3112 | 23.3 | 0.125* | ||
| CH3COCH3:CH3OH | 140 | 1346.1 | 7.4290 | – | – |
| 1350.9 | 7.4025 | – | – | ||
| 1364.4 | 7.3293 | 7.5 | 0.0404 | ||
| CH3COCH3:H2O:CO2 | 1356.7 | 7.3710 | – | – | |
| 1367.3 | 7.3138 | 23.3 | 0.125* | ||
| CH3COCH3:H2O:CH4 | 1365.6 | 7.3228 | 21.8 | ||
| CH3COCH3:CH3OH:CO | 1345.6 | 7.4317 | – | – | |
| 1349.9 | 7.4078 | – | – | ||
| 1364.4 | 7.3293 | 7.5 | 0.0404 | ||
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