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Table B.2.
Peak position and FWHM of the acetone CH3 asymmetric deformation mode for pure acetone and mixtures with acetone ratio 1:5 and for temperatures ranging from 15 K to 140 K. See also Figs. A.1 and A.2.
| Mixture | Temperature | Peak position |
FWHM |
||
|---|---|---|---|---|---|
| (K) | (cm−1) | (μm) | (cm−1) | (μm) | |
| CH3COCH3 | 1417.9 | 7.0527 | 40.9 | 0.199* | |
| 1441.0 | 6.9394 | – | – | ||
| CH3COCH3:CO | 1417.4 | 7.0551 | 8.7 | 0.0434 | |
| 1436.7 | 6.9604 | 15.1 | 0.0776* | ||
| CH3COCH3:CO2 | 15 | 1419.8 | 7.0431 | 11.4 | 0.0563 |
| 1444.2 | 6.9243 | – | – | ||
| CH3COCH3:H2O | 1421.5 | 7.0347 | 20.0 | 0.100* | |
| 1442.7 | 6.9313 | – | – | ||
| CH3COCH3:H2O:CO2 | 1422.0 | 7.0323 | 16.3 | 0.0804 | |
| 1444.4 | 6.9232 | – | – | ||
| CH3COCH3:H2O:CH4 | 1422.5 | 7.0299 | 15.7 | ||
| 1443.0 | 6.930 | 14.2 | |||
| CH3COCH3 | 1417.9 | 7.0527 | 40.9 | 0.199* | |
| 1441.3 | 6.9382 | – | – | ||
| CH3COCH3:CO | 1417.9 | 7.0527 | 8.7 | 0.0433 | |
| 1437.7 | 6.9557 | 14.2 | 0.0740 | ||
| CH3COCH3:CO2 | 30 | 1419.8 | 7.0431 | 11.3 | 0.0559 |
| 1443.9 | 6.9255 | – | – | ||
| CH3COCH3:H2O | 1421.0 | 7.0371 | 18.7 | 0.0923 | |
| 1441.3 | 6.9382 | – | – | ||
| CH3COCH3:H2O:CO2 | 1421.8 | 7.0335 | 16.1 | 0.0792* | |
| 1444.2 | 6.9243 | – | – | ||
| CH3COCH3:H2O:CH4 | 1422.2 | 7.0314 | 15.3 | ||
| 1442.7 | 6.9315 | 14.3 | |||
| CH3COCH3 | 1418.1 | 7.0515 | 39.6 | 0.193* | |
| 1441.0 | 6.9394 | – | – | ||
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | 1419.8 | 7.0431 | 12.5 | 0.0621 | |
| 1441.8 | 6.9359 | – | – | ||
| CH3COCH3:H2O | 70 | 1421.0 | 7.0371 | 18.7 | 0.0923 |
| 1441.3 | 6.9382 | – | – | ||
| CH3COCH3:H2O:CO2 | 1421.8 | 7.0335 | 15.6 | 0.0770* | |
| 1442.3 | 6.9336 | – | – | ||
| CH3COCH3:H2O:CH4 | 1422.2 | 7.0314 | 16.5 | ||
| 1442.5 | 6.9324 | 14.3 | |||
| CH3COCH3 | 1418.1 | 7.0515 | 38.7 | 0.189* | |
| 1440.8 | 6.9406 | – | – | ||
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | 1419.4 | 7.0455 | 15.6 | 0.0774 | |
| 1440.6 | 6.9417 | – | – | ||
| CH3COCH3:H2O | 90 | 1421.0 | 7.0371 | 18.5 | 0.0911 |
| 1439.5 | 6.9469 | – | – | ||
| CH3COCH3:H2O:CO2 | 1421.5 | 7.0347 | 15.8 | 0.0781* | |
| 1442.0 | 6.9348 | – | – | ||
| CH3COCH3:H2O:CH4 | 1421.8 | 7.0333 | 16.3 | ||
| 1441.3 | 6.9381 | 14.4 | |||
| CH3COCH3 | 1401.8 | 7.1339 | – | – | |
| 1417.4 | 7.0551 | 10.8 | 0.0538 | ||
| 1438.4 | 6.9522 | – | – | ||
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | 100 | 1418.9 | 7.0479 | 36.3 | 0.177* |
| 1440.1 | 6.9440 | – | – | ||
| CH3COCH3:H2O | 1421.0 | 7.0371 | 18.4 | 0.0906 | |
| 1439.1 | 6.9486 | – | – | ||
| CH3COCH3:H2O:CO2 | 1420.8 | 7.0383 | – | – | |
| 1440.1 | 6.9440 | 17.2 | 0.0849* | ||
| CH3COCH3:H2O:CH4 | 1421.8 | 7.0333 | 16.4 | ||
| 1441.3 | 6.9382 | 14.2 | |||
| CH3COCH3 | 1402.2 | 7.1315 | – | – | |
| 1417.7 | 7.0539 | 11.5 | 0.0569 | ||
| 1439.0 | 6.9495 | – | – | ||
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | – | – | – | – | |
| CH3COCH3:H2O | 110 | 1421.3 | 7.0359 | 18.5 | 0.0910 |
| 1440.0 | 6.9445 | – | – | ||
| CH3COCH3:H2O:CO2 | 1420.8 | 7.0383 | – | – | |
| 1440.1 | 6.9440 | 18.8 | 0.0925* | ||
| CH3COCH3:H2O:CH4 | 1421.8 | 7.0333 | 16.4 | ||
| 1441.3 | 6.9382 | 14.4 | |||
| CH3COCH3 | 1402.5 | 7.1302 | – | – | |
| 1417.9 | 7.0527 | 12.1 | 0.0599 | ||
| 1438.6 | 6.9510 | – | – | ||
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | 120 | – | – | – | – |
| CH3COCH3:H2O | 1421.0 | 7.0371 | 18.5 | 0.0913 | |
| 1439.5 | 6.9466 | – | – | ||
| CH3COCH3:H2O:CO2 | 1420.6 | 7.0395 | – | – | |
| 1439.8 | 6.9452 | 19.7 | 0.0971* | ||
| CH3COCH3:H2O:CH4 | 1421.3 | 7.0358 | 30.0 | ||
| 1439.6 | 6.9463 | 18.0 | |||
| CH3COCH3 | 1404.9 | 7.1180 | – | – | |
| 1417.7 | 7.0539 | 12.2 | 0.0607 | ||
| 1439.8 | 6.9452 | – | – | ||
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | 140 | – | – | – | – |
| CH3COCH3:H2O | 1420.3 | 7.0407 | 25.8 | 0.127 | |
| CH3COCH3:H2O:CO2 | 1420.3 | 7.0407 | – | – | |
| 1431.2 | 6.9873 | 29.4 | 0.144* | ||
| CH3COCH3:H2O:CH4 | 1421.5 | 7.0348 | 29.7 | ||
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