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Table B.8.
Peak position and FWHM of the acetone CH3 symmetric deformation mode for pure acetone and mixtures with acetone ratio 1:20 and for temperatures ranging from 15 K to 140 K. See also Figs. A.11 and A.12.
| Mixture | Temperature | Peak position |
FWHM |
||
|---|---|---|---|---|---|
| (K) | (cm−1) | (μm) | (cm−1) | (μm) | |
| CH3COCH3 | 1363.4 | 7.3345 | 19.2 | 0.0640 | |
| CH3COCH3:CO | 1353.3 | 7.3893 | 6.1 | 0.0332 | |
| 1363.9 | 7.3319 | 5.7 | 0.0308 | ||
| CH3COCH3:CO2 | 1356.9 | 7.3696 | 6.6 | 0.0358 | |
| 1367.5 | 7.3125 | 6.2 | 0.0333 | ||
| CH3COCH3:H2O | 15 | 1358.1 | 7.3631 | – | – |
| 1371.9 | 7.2894 | 13.2 | 0.180 | ||
| CH3COCH3:CH3OH | 1367.3 | 7.3138 | 16.3 | 0.0870* | |
| CH3COCH3:H2O:CO2 | 1359.3 | 7.3566 | – | – | |
| 1372.6 | 7.2855 | 11.1 | 0.0588 | ||
| CH3COCH3:H2O:CH4 | 1359.8 | 7.354 | 10.7 | ||
| 1373.1 | 7.2828 | 10.9 | |||
| CH3COCH3:CH3OH:CO | 1356.7 | 7.3710 | – | – | |
| 1370.4 | 7.2971 | 14.6 | 0.0779 | ||
| CH3COCH3 | 1363.2 | 7.3358 | 19.7 | 0.106 | |
| CH3COCH3:CO | 1352.8 | 7.3920 | 8.1 | 0.0408 | |
| 1363.9 | 7.3319 | 7.6 | 0.0440 | ||
| CH3COCH3:CO2 | 1356.7 | 7.3710 | – | – | |
| 1367.5 | 7.3125 | 6.6 | 0.0353 | ||
| CH3COCH3:H2O | 30 | 1358.1 | 7.3631 | – | – |
| 1371.6 | 7.2906 | 13.5 | 0.0717 | ||
| CH3COCH3:CH3OH | 1366.8 | 7.3164 | 16.6 | 0.0888 | |
| CH3COCH3:H2O:CO2 | 1359.1 | 7.3579 | – | – | |
| 1372.3 | 7.2868 | 11.3 | 0.0600 | ||
| CH3COCH3:H2O:CH4 | 1360.3 | 7.3513 | 10.5 | ||
| 1372.8 | 7.2843 | 10.7 | |||
| CH3COCH3:CH3OH:CO | 1356.4 | 7.3723 | – | – | |
| 1370.7 | 7.2958 | 14.0 | 0.0745 | ||
| CH3COCH3 | 1363.2 | 7.3358 | 20.8 | 0.112 | |
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | 1365.1 | 7.3254 | 16.5 | 0.0888 | |
| CH3COCH3:H2O | 1357.2 | 7.3683 | – | – | |
| 1369.9 | 7.2996 | 15.5 | 0.0826 | ||
| CH3COCH3:CH3OH | 70 | 1364.4 | 7.3293 | 16.9 | 0.0909 |
| CH3COCH3:H2O:CO2 | 1359.1 | 7.3579 | – | – | |
| 1372.1 | 7.2881 | 11.7 | 0.0623 | ||
| CH3COCH3:H2O:CH4 | 1359.6 | 7.3551 | 10.5 | ||
| 1372.8 | 7.284 | 13.3 | |||
| CH3COCH3:CH3OH:CO | 1354.3 | 7.3841 | – | – | |
| 1364.1 | 7.3306 | 11.6 | 0.0623 | ||
| CH3COCH3 | 1363.2 | 7.3358 | 21.0 | 0.113 | |
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | 1365.1 | 7.3254 | 16.5 | 0.0892 | |
| CH3COCH3:H2O | 1356.9 | 7.3696 | – | – | |
| 1369.7 | 7.3009 | 22.4 | 0.120* | ||
| CH3COCH3:CH3OH | 90 | 1363.7 | 7.3332 | 15.9 | 0.0852 |
| CH3COCH3:H2O:CO2 | 1359.1 | 7.3579 | – | – | |
| 1371.9 | 7.2894 | 12.3 | 0.0656 | ||
| CH3COCH3:H2O:CH4 | 1359.8 | 7.354 | 10.3 | ||
| 1372.8 | 7.284 | 14.1 | |||
| CH3COCH3:CH3OH:CO | 1354.3 | 7.3841 | – | – | |
| 1363.7 | 7.3332 | 12.0 | 0.0644 | ||
| CH3COCH3 | 1345.3 | 7.4330 | 7.7 | 0.0424* | |
| 1349.2 | 7.4118 | – | – | ||
| 1361.3 | 7.3462 | 8.8 | 0.0472 | ||
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | 1351.1 | 7.4012 | – | – | |
| 1369.7 | 7.3009 | 14.0 | 0.0750 | ||
| CH3COCH3:H2O | 100 | 1356.9 | 7.3696 | – | – |
| 1369.7 | 7.3009 | 22.5 | 0.120 | ||
| CH3COCH3:CH3OH | 1363.7 | 7.3332 | 15.5 | 0.0834* | |
| CH3COCH3:H2O:CO2 | 1358.4 | 7.3618 | – | – | |
| 1371.1 | 7.2932 | 22.4 | 0.1200 | ||
| CH3COCH3:H2O:CH4 | 1360.3 | 7.351 | 10.3 | ||
| 1372.8 | 7.284 | 14.4 | |||
| CH3COCH3:CH3OH:CO | 1354.5 | 7.3831 | – | – | |
| 1363.7 | 7.3332 | 12.5 | 0.0674 | ||
| CH3COCH3 | 1345.6 | 7.4317 | 7.5 | 0.0413* | |
| 1349.2 | 7.4118 | – | – | ||
| 1361.0 | 7.3475 | 8.7 | 0.0471 | ||
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | – | – | – | – | |
| CH3COCH3:H2O | 110 | 1356.9 | 7.3696 | – | – |
| 1369.5 | 7.3022 | 22.6 | 0.121* | ||
| CH3COCH3:CH3OH | 1363.4 | 7.3345 | 19.9 | 0.107 | |
| CH3COCH3:H2O:CO2 | 1358.1 | 7.3631 | – | – | |
| 1369.9 | 7.2996 | 22.2 | 0.119* | ||
| CH3COCH3:H2O:CH4 | 1359.8 | 7.354 | 9.5 | ||
| 1372.8 | 7.284 | 15.0 | |||
| CH3COCH3:CH3OH:CO | 1349.9 | 7.4078 | – | – | |
| 1363.7 | 7.3332 | 12.1 | 0.0650 | ||
| CH3COCH3 | 1346.1 | 7.4290 | 7.3 | 0.0404* | |
| 1349.4 | 7.4105 | – | – | ||
| 1360.8 | 7.3488 | 8.7 | 0.0470 | ||
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | – | – | – | – | |
| CH3COCH3:H2O | 120 | 1356.7 | 7.3710 | – | – |
| 1369.5 | 7.3022 | 22.6 | 0.121* | ||
| CH3COCH3:CH3OH | 1363.7 | 7.3332 | 24.6 | 0.133* | |
| CH3COCH3:H2O:CO2 | 1356.9 | 7.3696 | – | – | |
| 1369.9 | 7.2996 | 22.6 | 0.121* | ||
| CH3COCH3:H2O:CH4 | 1372.6 | 7.285 | 15.6 | ||
| 1359.8 | 7.354 | 8.7 | |||
| CH3COCH3:CH3OH:CO | 1345.1 | 7.4344 | – | – | |
| 1349.7 | 7.4091 | – | – | ||
| 1363.7 | 7.3332 | 10.9 | 0.0583 | ||
| CH3COCH3 | 1346.6 | 7.4264 | – | – | |
| 1350.9 | 7.4025 | – | – | ||
| 1361.7 | 7.3436 | 9.3 | 0.0499 | ||
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | – | – | – | – | |
| CH3COCH3:H2O | 1356.7 | 7.3710 | – | – | |
| 1369.2 | 7.3035 | 23.1 | 0.124* | ||
| CH3COCH3:CH3OH | 140 | 1363.7 | 7.3332 | 14.0 | 0.0753 |
| CH3COCH3:H2O:CO2 | 1356.4 | 7.3723 | – | – | |
| 1364.9 | 7.3267 | 20.5 | 0.110* | ||
| CH3COCH3:H2O:CH4 | 1366.1 | 7.320 | – | ||
| CH3COCH3:CH3OH:CO | – | – | – | – | |
| CH3COCH3 | – | – | – | – | |
| CH3COCH3:CO | – | – | – | – | |
| CH3COCH3:CO2 | – | – | – | – | |
| CH3COCH3:H2O | 160 | 1357.5 | 7.3666 | – | – |
| 1367.0 | 7.3151 | 23.3 | 0.125 | ||
| CH3COCH3:CH3OH | – | – | – | – | |
| CH3COCH3:H2O:CO2 | – | – | – | – | |
| CH3COCH3:H2O:CH4 | – | – | – | ||
| CH3COCH3:CH3OH:CO | – | – | – | – | |
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