Open Access
Table 4
Relative energies at the MPWB1K (kcal mol−1) for the reaction profile given in Fig. 4 for OH(2Π) + OH(2 Π) → H2O(1A1) + O(3 P) in presence of water bilayers.
Single bilayer 24 molecules(1-L) | Double bilayer 48 molecules(2-L) | |||||||
---|---|---|---|---|---|---|---|---|
aug-cc-pVTZ | 6-311++G(3df,2p) | 6-311++G(3df,2p | 6-311++G(3df,2p | |||||
no opt | no opt | no opt | 6 H2O opt | |||||
Ee | E0 | Ee | E0 | Ee | E0 | Ee | E0 | |
[Layer-OH](2A) + OH(2Π) | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 |
[Layer-OH-OH](3A) | −13.9 | −11.8 | −14.2 | −12.1 | −13.6 | −11.4 | −9.7 | −7.5 |
[Layer-TS](3A) | −0.8 | −1.7 | −0.9 | −1.8 | −0.6 | −1.6 | −0.6 | −1.2 |
[Layer-H2O] -O(3P) | −21.1 | −17.5 | −21.7 | −18.1 | −21.6 | −18.2 | −21.4 | −17.6 |
[Layer-H2O](2A) + O(3P) | −18.1 | −15.2 | −18.2 | −15.3 | −18.6 | −15.6 | −17.2 | −13.8 |
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