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Table 1.
MnH molecular states in the asymptotic atomic state representation, i.e. possible scattering channels, and associated input data.
| TermA | LA | 2SA + 1 | n | l |  [cm−1] |
Elim [cm−1] | Ej[cm−1] | Neq | Termc | Lc | 2Sc + 1 |  |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Covalent states: Mn((2Sc + 1Lc) nl2SA + 1LA)+H(1s 2S) | ||||||||||||
| a6S | 0 | 6 | 4 | 0 | 0 | 59 960 | 0 | 2 | a7S | 0 | 7 | 0.764 |
| a6S | 0 | 6 | 4 | 0 | 0 | 69 433 | 0 | 2 | a5S | 0 | 5 | −0.645 |
| a6D | 2 | 6 | 4 | 0 | 17 301 | 74 546 | 17 301 | 1 | a5D | 2 | 5 | 1.000 |
| z8Po | 1 | 8 | 4 | 1 | 18 572 | 59 960 | 18 572 | 1 | a7S | 0 | 7 | 1.000 |
| a4D | 2 | 4 | 4 | 0 | 23 509 | 74 546 | 23 509 | 1 | a5D | 2 | 5 | 1.000 |
| z6Po | 1 | 6 | 4 | 1 | 24 792 | 59 960 | 24 792 | 1 | a7S | 0 | 7 | 1.000 |
| z6Po | 1 | 6 | 4 | 1 | 24 792 | 69 433 | 24 792 | 1 | a5S | 0 | 5 | 1.000 |
| a4G | 4 | 4 | 4 | 0 | 25 279 | 87 531 | 25 279 | 2 | a5G | 4 | 5 | 0.791 |
| a4G | 4 | 4 | 4 | 0 | 25 279 | 93 175 | 25 279 | 2 | a3G | 4 | 3 | −0.612 |
| a4G | 1 | 4 | 4 | 0 | 27 230 | 87 531 | 27 230 | 2 | a5G | 4 | 5 | 0.791 |
| a4G | 1 | 4 | 4 | 0 | 27 230 | 93 175 | 27 230 | 2 | a3G | 4 | 3 | −0.612 |
| b4D | 2 | 4 | 4 | 0 | 30 394 | 92 789 | 30 394 | 2 | b5D | 2 | 5 | 0.791 |
| b4D | 2 | 4 | 4 | 0 | 30 394 | 99 774 | 30 394 | 2 | b3D | 2 | 3 | −0.612 |
| z4Po | 1 | 4 | 4 | 1 | 31 047 | 69 433 | 31 047 | 1 | a5S | 0 | 5 | 1.000 |
| b4P | 1 | 4 | 4 | 0 | 34 208 | 90 229 | 34 208 | 1 | a3P | 1 | 3 | 1.000 |
| a4H | 5 | 4 | 4 | 0 | 34 268 | 90 610 | 34 268 | 1 | a3H | 5 | 3 | 1.000 |
| a4F | 3 | 4 | 4 | 0 | 35 038 | 91 583 | 35 038 | 1 | a3F | 3 | 3 | 1.000 |
| y6Po | 1 | 6 | 4 | 1 | 35 737 | 59 960 | 35 737 | 1 | a7S | 0 | 7 | 1.000 |
| y6Po | 1 | 6 | 4 | 1 | 35 737 | 69 433 | 35 737 | 1 | a5S | 0 | 5 | 1.000 |
| a2I | 6 | 2 | 4 | 0 | 37 157 | 101 151 | 37 157 | 2 | a3I | 6 | 3 | 0.866 |
| ⋯ ⋯ ⋯ | ||||||||||||
| z8Fo | 3 | 8 | 4 | 3 | 52 975 | 59 960 | 52 975 | 1 | a7S | 0 | 7 | 1.000 |
| w6Fo | 3 | 6 | 4 | 3 | 52 978 | 59 960 | 52 978 | 1 | a7S | 0 | 7 | 1.000 |
| y4Do | 2 | 4 | 4 | 1 | 53 133 | 89 872 | 53 133 | 1 | a5P | 1 | 5 | 1.000 |
| y4Do | 2 | 4 | 4 | 1 | 53 133 | 96 282 | 53 133 | 1 | b3P | 1 | 3 | 1.000 |
| t8Po | 1 | 6 | 6 | 1 | 53 282 | 59 960 | 53 282 | 1 | a7S | 0 | 7 | 1.000 |
| Ionic states: Mn+(2SA + 1LA)+H−(1s21S) |  [cm−1] |
Ej[cm−1] | ||||||||||
| a7S | 0 | 7 | – | – | 59 960 | – | 53 877 | |||||
| a5S | 0 | 5 | – | – | 69 433 | – | 63 350 | |||||
| a5D | 2 | 5 | – | – | 74 546 | – | 68 463 | |||||
| a5G | 4 | 5 | – | – | 87 531 | – | 81 448 | |||||
| a3P | 1 | 3 | – | – | 90 229 | – | 84 146 | |||||
| a5P | 1 | 5 | – | – | 89 872 | – | 83 789 | |||||
| a3H | 5 | 3 | – | – | 90 610 | – | 84 527 | |||||
| a3F | 3 | 3 | – | – | 91 583 | – | 85 500 | |||||
| b5D | 2 | 5 | – | – | 92 789 | – | 86 706 | |||||
| a3G | 4 | 3 | – | – | 93 175 | – | 87 092 | |||||
| b3G | 4 | 3 | – | – | 94 835 | – | 88 752 | |||||
| b3P | 1 | 3 | – | – | 96 282 | – | 90 199 | |||||
| a3D | 2 | 3 | – | – | 97 802 | – | 91 719 | |||||
| z7Po | 1 | 7 | – | – | 98 574 | – | 92 491 | |||||
| a1I | 6 | 1 | – | – | 98 680 | – | 92 597 | |||||
| a1G | 4 | 1 | – | – | 98 862 | – | 92 779 | |||||
| b3D | 2 | 3 | – | – | 99 774 | – | 93 691 | |||||
| a3I | 6 | 3 | – | – | 101 151 | – | 95 068 | |||||
| b1I | 6 | 1 | – | – | 104 275 | – | 98 192 | |||||
| c3P | 1 | 3 | – | – | 113 266 | – | 107 183 | |||||
| e3F | 3 | 3 | – | – | 113 732 | – | 107 649 | |||||
Notes. See the text for further details.
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