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Table A.7
Radial parameters (in cm−1) adopted for the calculations in Cu VI.
| Configuration | Parameter | HFR | Fitted | Ratio | Note (a) |
|---|---|---|---|---|---|
| Even parity | |||||
| 3d6 | Eav | 47 058 | 46 817 | ||
| F2(3d,3d) | 127 114 | 112 843 | 0.888 | ||
| F4(3d,3d) | 80 096 | 69 557 | 0.868 | ||
| α | 0 | 103 | |||
| β | 0 | − 264 | |||
| ζ3d | 1080 | 1142 | 1.057 | ||
| 3d54s | Eav | 332 771 | 334 360 | ||
| F2(3d,3d) | 132 805 | 116 707 | 0.879 | ||
| F4(3d,3d) | 83 932 | 74 133 | 0.883 | ||
| α | 0 | 100 | F | ||
| β | 0 | −250 | F | ||
| ζ3d | 1161 | 1161 | 1.000 | F | |
| G2(3d,4s) | 13 493 | 12 647 | 0.937 | ||
| Odd parity | |||||
| 3d54p | Eav | 424 263 | 425 870 | ||
| F2(3d,3d) | 133 032 | 116 189 | 0.873 | ||
| F4(3d,3d) | 84 088 | 72 010 | 0.856 | ||
| α | 0 | 127 | |||
| β | 0 | − 286 | |||
| ζ3d | 1163 | 1247 | 1.073 | ||
| ζ4p | 2028 | 2320 | 1.144 | ||
| F2(3d,4p) | 31 832 | 30 768 | 0.967 | ||
| G1(3d,4p) | 10 697 | 10 190 | 0.953 | ||
| G3(3d,4p) | 10 151 | 9203 | 0.907 | ||
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