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Table A.7

Radial parameters (in cm−1) adopted for the calculations in Cu VI.

Configuration Parameter HFR Fitted Ratio Note (a)
Even parity
3d6 Eav 47 058 46 817
F2(3d,3d) 127 114 112 843 0.888
F4(3d,3d) 80 096 69 557 0.868
α 0 103
β 0 − 264
ζ3d 1080 1142 1.057
3d54s Eav 332 771 334 360
F2(3d,3d) 132 805 116 707 0.879
F4(3d,3d) 83 932 74 133 0.883
α 0 100 F
β 0 −250 F
ζ3d 1161 1161 1.000 F
G2(3d,4s) 13 493 12 647 0.937
           
Odd parity
3d54p Eav 424 263 425 870
F2(3d,3d) 133 032 116 189 0.873
F4(3d,3d) 84 088 72 010 0.856
α 0 127
β 0 − 286
ζ3d 1163 1247 1.073
ζ4p 2028 2320 1.144
F2(3d,4p) 31 832 30 768 0.967
G1(3d,4p) 10 697 10 190 0.953
G3(3d,4p) 10 151 9203 0.907

Notes. (a) F: parameter fixed to its ab initio value.

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