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Table A.6
Radial parameters (in cm−1) adopted for the calculations in Cu V.
Configuration | Parameter | HFR | Fitted | Ratio | Note (a) |
---|---|---|---|---|---|
Even parity | |||||
3d7 | Eav | 30 899 | 30 322 | ||
F2(3d,3d) | 119 816 | 105 551 | 0.881 | ||
F4(3d,3d) | 75 176 | 65 503 | 0.871 | ||
α | 0 | 109 | |||
β | 0 | − 587 | |||
ζ3d | 989 | 1002 | 1.013 | ||
3d64s | Eav | 234 957 | 237 924 | ||
F2(3d,3d) | 125 814 | 110 315 | 0.877 | ||
F4(3d,3d) | 79 209 | 67 072 | 0.847 | ||
α | 0 | 117 | |||
β | 0 | −154 | |||
ζ3d | 1066 | 1154 | 1.082 | ||
G2(3d,4s) | 12 797 | 11 794 | 0.922 | ||
Odd parity | |||||
3d64p | Eav | 316 597 | 319 750 | ||
F2(3d,3d) | 126 094 | 109 170 | 0.866 | ||
F4(3d,3d) | 79 402 | 66 055 | 0.832 | ||
α | 0 | 114 | |||
β | 0 | 213 | |||
ζ3d | 1069 | 1180 | 1.104 | ||
ζ4p | 1596 | 1816 | 1.137 | ||
F2(3d,4p) | 28 011 | 26 960 | 0.962 | ||
G1(3d,4p) | 9612 | 9190 | 0.956 | ||
G3(3d,4p) | 8916 | 7838 | 0.879 |
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