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Table A.6

Radial parameters (in cm−1) adopted for the calculations in Cu V.

Configuration Parameter HFR Fitted Ratio Note (a)
Even parity
3d7 Eav 30 899 30 322
F2(3d,3d) 119 816 105 551 0.881
F4(3d,3d) 75 176 65 503 0.871
α 0 109
β 0 − 587
ζ3d 989 1002 1.013
3d64s Eav 234 957 237 924
F2(3d,3d) 125 814 110 315 0.877
F4(3d,3d) 79 209 67 072 0.847
α 0 117
β 0 −154
ζ3d 1066 1154 1.082
G2(3d,4s) 12 797 11 794 0.922
           
Odd parity
3d64p Eav 316 597 319 750
F2(3d,3d) 126 094 109 170 0.866
F4(3d,3d) 79 402 66 055 0.832
α 0 114
β 0 213
ζ3d 1069 1180 1.104
ζ4p 1596 1816 1.137
F2(3d,4p) 28 011 26 960 0.962
G1(3d,4p) 9612 9190 0.956
G3(3d,4p) 8916 7838 0.879

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