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Table A.12

Comparison between available experimental and calculated energy levels in Cu VII.

Eexp (a) Ecalc (b) ΔE J Leading components (in %) in LS coupling (c)
Even parity
0.0 −13 13 2.5 100 3d5 6S
46 442.7 46 565 −122 5.5 100 3d5 4G
46 515.3 46 383 132 2.5 99 3d5 4G
46 575.0 46 604 −29 4.5 100 3d5 4G
46 578.2 46 520 58 3.5 99 3d5 4G
50 731.7 50 742 −10 2.5 86 3d5 4P + 12 3d5 4D
51 066.6 51 059 8 1.5 89 3d5 4P + 10 3d5 4D
51 406.6 51 420 −13 0.5 96 3d5 4P
55 742.2 55 792 −50 3.5 99 3d5 4D
56 209.9 56 168 42 0.5 96 3d5 4D
56 427.2 56 473 −46 2.5 87 3d5 4D + 12 3d5 4P
56 428.5 56 434 −6 1.5 89 3d5 4D + 10 3d5 4P
67 757.3 67 660 97 5.5 98 3d5 2I
67 917.9 67 993 −75 6.5 100 3d5 2I
70 875.6 70 762 114 2.5 49 3d5 2D + 32 3d5 2F + 15 3d5 2D
72 226.8 72 213 14 1.5 68 3d5 2D + 21 3d5 2D + 11 3d5 4F
74 407.6 74 668 −260 3.5 92 3d5 2F + 5 3d5 4F
75 930.5 75 980 −50 4.5 93 3d5 4F + 6 3d5 2G
76 019.0 76 095 −76 2.5 73 3d5 4F + 22 3d5 2F
76 349.1 76 277 72 3.5 91 3d5 4F + 6 3d5 2F
76 886.0 76 876 10 1.5 89 3d5 4F + 9 3d5 2D
77 529.3 77 389 140 2.5 44 3d5 2F + 24 3d5 2D + 23 3d5 4F
80 717.0 80 653 64 4.5 71 3d5 2H + 25 3d5 2G
81 954.4 81 992 −38 5.5 97 3d5 2H
82 745.5 82 790 −45 3.5 97 3d5 2G
83 910.4 83 935 −25 4.5 68 3d5 2G + 28 3d5 2H
87 979.2 88 025 −46 2.5 97 3d5 2F
88 279.7 88 128 152 3.5 97 3d5 2F
95 875.4 95 932 −57 0.5 100 3d5 2S
106 957.0 106 878 79 1.5 100 3d5 2D
107 130.6 107 135 −4 2.5 99 3d5 2D
119 534.0 119 545 −11 4.5 100 3d5 2G
119 605.4 119 648 −43 3.5 99 3d5 2G
143 933.7 143 910 24 1.5 99 3d5 2P
144 077.2 144 131 −54 0.5 100 3d5 2P
156 224.4 156 181 43 2.5 77 3d5 2D + 23 3d5 2D
156 373.6 156 377 −3 1.5 76 3d5 2D + 23 3d5 2D
         
Odd parity
497 624.0 497 489 135 1.5 90 3d4(5D)4p 6P + 7 3d4(5D)4p 4P
497 863.0 497 657 206 2.5 93 3d4(5D)4p 6P
498 317.0 498 057 260 3.5 98 3d4(5D)4p 6P
498 775.0 499 069 −294 0.5 65 3d4(5D)4p 4P + 32 3d4(5D)4p 6D
500 706.0 500 802 −96 1.5 51 3d4(5D)4p 4P + 36 3d4(5D)4p 6D + 10 3d4(5D)4p 6P
502 909.0 502 882 27 2.5 58 3d4(5D)4p 6D + 34 3d4(5D)4p 4P + 6 3d4(5D)4p 6P
504 338.0 504 276 62 0.5 68 3d4(5D)4p 6D + 31 3d4(5D)4p 4P
504 729.0 504 631 98 1.5 60 3d4(5D)4p 6D + 38 3d4(5D)4p 4P
505 447.0 505 280 167 2.5 59 3d4(5D)4p 4P + 38 3d4(5D)4p 6D
508 524.0 508 408 116 1.5 94 3d4(5D)4p 4F
508 877.0 508 703 174 2.5 92 3d4(5D)4p 4F
509 418.0 509 167 251 3.5 89 3d4(5D)4p 4F + 5 3d4(5D)4p 6D
510 250.0 509 928 322 4.5 81 3d4(5D)4p 4F + 14 3d4(5D)4p 6D
517 847.0 518 055 −208 0.5 96 3d4(5D)4p 4D
518 282.0 518 443 −161 1.5 96 3d4(5D)4p 4D
518 863.0 518 976 −113 2.5 96 3d4(5D)4p 4D
519 415.0 519 509 −94 3.5 96 3d4(5D)4p 4D
528 494.0 528 566 −72 3.5 74 3d4(3H)4p 4H + 21 3d4(3G)4p 4H
529 027.0 529 068 −41 4.5 69 3d4(3H)4p 4H + 19 3d4(3G)4p 4H + 8 3d4(3H)4p 4I
529 891.0 529 884 7 5.5 70 3d4(3H)4p 4H + 17 3d4(3G)4p 4H + 11 3d4(3H)4p 4I
531 047.0 531 008 39 6.5 76 3d4(3H)4p 4H + 13 3d4(3G)4p 4H + 9 3d4(3H)4p 4I
532 460.0 532 075 385 2.5 40 3d4 (3 P)4p 4D + 26 3d4(3P)4p 4D + 17 3d4(3F)4p 4D
533 066.0 533 079 −13 3.5 27 3d4 (3 F)4p 4G + 17 3d4(3G)4p 4G + 14 3d4(3F)4p 4G
533 103.0 532 965 138 4.5 58 3d4 (3 H)4p 4I + 8 3d4(3H)4p 4H + 7 3d4(3H)4p 2G
533 685.0 533 587 98 0.5 41 3d4 (3 P)4p 4P + 22 3d4(3P)4p 4P + 15 3d4(3P)4p 2S
534 128.0 533 733 395 4.5 29 3d4 (3 H)4p 4I + 14 3d4(3F)4p 4G + 13 3d4(3H)4p 4G
534 204.0 533 796 408 3.5 31 3d4 (3 F)4p 4D + 25 3d4(3P)4p 4D + 16 3d4(3P)4p 4D
534 912.0 534 654 258 5.5 67 3d4 (3 H)4p 4I + 11 3d4(3H)4p 4G + 11 3d4(3H)4p 4H
535 632.0 535 162 470 5.5 38 3d4 (3 H)4p 4G + 25 3d4(3G)4p 4G + 19 3d4(3H)4p 4I
536 229.0 536 291 −62 1.5 55 3d4 (3 P)4p 4P + 29 3d4(3P)4p 4P
536 650.0 536 534 116 4.5 31 3d4 (3 H)4p 2G + 20 3d4(3F)4p 2G + 14 3d4(3G)4p 4G
537 169.0 537 180 −11 2.5 33 3d4 (3 H)4p 4G + 27 3d4(3F)4p 4G + 14 3d4(3G)4p 4G
537 802.0 537 633 169 3.5 46 3d4 (3 H)4p 4G + 32 3d4(3F)4p 4G + 14 3d4(3G)4p 4G
537 874.0 537 807 67 2.5 44 3d4 (3 F)4p 4F + 11 3d4(3F)4p 2D + 9 3d4(3H)4p 4G
538 144.0 537 939 205 4.5 42 3d4 (3 F)4p 4G + 36 3d4(3H)4p 4G + 7 3d4(3F)4p 4G
538 624.0 538 331 293 2.5 54 3d4 (3 P)4p 4P + 28 3d4(3P)4p 4P + 5 3d4(3P)4p 2D
538 749.0 538 777 −28 3.5 60 3d4 (3 F)4p 4F + 11 3d4(3F)4p 4F + 10 3d4(3G)4p 4F
539 041.0 538 800 241 5.5 60 3d4 (3 F)4p 4G + 18 3d4(3H)4p 4G + 13 3d4(3F)4p 4G
539 146.0 539 272 −126 4.5 54 3d4 (3 F)4p 4F + 15 3d4(3G)4p 4F + 10 3d4(3F)4p 4F
539 640.0 539 940 −300 2.5 14 3d4 (3 F)4p 2D + 14 3d4(3G)4p 4F + 12 3d4(3G)4p 2F
540 086.0 540 131 −45 1.5 21 3d4 (3 F)4p 2D + 21 3d4(3F)4p 4F + 9 3d4(3D)4p 2D
540 915.0 540 877 38 1.5 37 3d4 (3 F)4p 4D + 13 3d4(3F)4p 4D + 10 3d4(3G)4p 4F
540 925.0 540 904 21 3.5 22 3d4 (3 G)4p 4F + 22 3d4(3P)4p 4D + 14 3d4(3P)4p 4D
541 444.0 541 807 −363 2.5 27 3d4 (3 G)4p 2F + 14 3d4(3D)4p 2F + 12 3d4(3F)4p 4D
541 457.0 541 680 −223 4.5 31 3d4 (3 H)4p 2H + 26 3d4(3G)4p 4H + 12 3d4(3G)4p 2H
541 509.0 540 981 528 6.5 82 3d4 (3 H)4p 2I + 11 3d4(3G)4p 4H
541 884.0 541 745 139 3.5 69 3d4(3G)4p 4H + 21 3d4(3H)4p 4H
542 239.0 542 259 −20 4.5 49 3d4(3G)4p 4F + 18 3d4(3F)4p 4F + 9 3d4(3D)4p 4F
542 362.0 542 676 −314 3.5 16 3d4(3G)4p 2F + 16 3d4(3D)4p 2F + 16 3d4(3G)4p 4F
542 394.0 542 133 261 1.5 21 3d4(3G)4p 4F + 14 3d4(3F)4p 4F
542 776.0 542 901 −125 2.5 37 3d4(3G)4p 4F + 15 3d4(3F)4p 4F + 15 3d4(3F)4p 4D
543 188.0 543 060 128 5.5 36 3d4(3G)4p 4H + 26 3d4(3H)4p 2H + 16 3d4(3G)4p 2H
543 217.0 543 139 78 3.5 24 3d4(3F)4p 4D + 19 3d4(3G)4p 4F + 10 3d4(3F)4p 4F
543 244.0 543 002 242 1.5 22 3d4(3G)4p 4F + 19 3d4(3P)4p 2P + 14 3d4(3F)4p 4D
543 574.0 543 293 281 4.5 48 3d4(3G)4p 4H + 23 3d4(3H)4p 2H + 11 3d4(3H)4p 4H
544 873.0 544 242 631 1.5 36 3d4(3P)4p 2D + 23 3d4(3P)4p 2D + 9 3d4(3G)4p 4F
546 268.0 545 746 522 2.5 41 3d4(3P)4p 2D + 26 3d4(3P)4p 2D + 5 3d4(3P)4p 4P
546 771.0 546 378 393 2.5 55 3d4(3F)4p 2F + 20 3d4(3G)4p 2F + 5 3d4(3P)4p 2D
546 881.0 546 990 −109 3.5 26 3d4(3F)4p 2G + 15 3d4(3F)4p 2G + 14 3d4(3H)4p 2G
547 090.0 547 235 −145 5.5 38 3d4(3G)4p 2H + 18 3d4(3H)4p 2H + 16 3d4(3G)4p 4G
547 381.0 547 495 −114 4.5 23 3d4(3F)4p 2G + 12 3d4(3F)4p 2G + 12 3d4(3G)4p 2G
547 565.0 547 500 65 3.5 50 3d4(3F)4p 2F + 30 3d4(3G)4p 2F
548 001.0 547 913 88 2.5 52 3d4(3G)4p 4G + 32 3d4(3H)4p 4G + 5 3d4(3F)4p 2F
548 491.0 548 364 127 3.5 49 3d4(3G)4p 4G + 24 3d4(3H)4p 4G + 6 3d4(3F)4p 2G
549 249.0 549 135 114 4.5 40 3d4(3G)4p 4G + 18 3d4(3H)4p 4G + 13 3d4(3G)4p 2H
550 007.0 549 870 137 5.5 46 3d4(3G)4p 4G + 21 3d4(3G)4p 2H + 18 3d4(3H)4p 4G
550 053.0 550 667 −614 2.5 61 3d4(3D)4p 4P + 26 3d4(3D)4p 4D + 5 3d4(3P)4p 4P
551 508.0 552 407 −899 3.5 75 3d4(3D)4p 4D + 7 3d4(3D)4p 4F + 5 3d4(3G)4p 4F
551 743.0 552 463 −720 2.5 48 3d4(3D)4p 4D + 26 3d4(3D)4p 4P + 8 3d4(3D)4p 4F
551 903.0 551 648 255 6.5 60 3d4(1I)4p 2I + 34 3d4(1I)4p 2K + 6 3d4(3H)4p 2I
552 334.0 553 189 −855 3.5 46 3d4(1G)4p 2F + 20 3d4(1G)4p 2F + 18 3d4(3G)4p 2G
552 359.0 552 167 192 5.5 88 3d4(1I)4p 2I
553 130.0 553 419 −289 1.5 69 3d4(3D)4p 4P + 11 3d4(3D)4p 4D + 7 3d4(3D)4p 4F
553 490.0 553 853 −363 4.5 51 3d4(3G)4p 2G + 21 3d4(3H)4p 2G + 11 3d4(1G)4p 2G
553 703.0 553 770 −67 3.5 49 3d4(3G)4p 2G + 17 3d4(3H)4p 2G + 9 3d4(1G)4p 2F
553 950.0 554 244 −294 0.5 87 3d4 (3 D)4p 4P + 7 3d4(3P)4p 4P
554 123.0 554 268 −145 4.5 47 3d4 (1 G)4p 2H + 21 3d4(1G)4p 2H + 10 3d4(3G)4p 2H
554 201.0 555 068 −867 0.5 39 3d4 (3 D)4p 2P + 35 3d4(1S)4p 2P + 9 3d4(3D)4p 4D
555 069.0 555 490 −421 5.5 54 3d4 (1 G)4p 2H + 18 3d4(1G)4p 2H + 11 3d4(1I)4p 2H
555 137.0 556 274 −1137 1.5 62 3d4 (3 D)4p 2P + 19 3d4(1S)4p 2P + 6 3d4(3D)4p 4D
555 295.0 554 827 468 6.5 64 3d4 (1 I)4p 2K + 35 3d4(1I)4p 2I
555 314.0 555 863 −549 2.5 49 3d4 (1 G)4p 2F + 23 3d4(1G)4p 2F + 6 3d4(3G)4p 2F
555 395.0 555 919 −524 3.5 63 3d4 (3 D)4p 4F + 19 3d4(3G)4p 4F + 12 3d4(3D)4p 4D
555 800.0 556 340 −540 4.5 76 3d4 (3 D)4p 4F + 19 3d4(3G)4p 4F
558 348.0 559 260 −912 3.5 45 3d4 (1 G)4p 2G + 30 3d4(1G)4p 2G + 9 3d4(3G)4p 2G
559 339.0 560 050 −711 4.5 42 3d4 (1 G)4p 2G + 32 3d4(1G)4p 2G + 18 3d4(3G)4p 2G
560 328.0 560 307 21 1.5 34 3d4 (1 D)4p 2D + 18 3d4(1S)4p 2P
560 658.0 560 942 −284 5.5 65 3d4 (1 I)4p 2H + 13 3d4(1G)4p 2H + 9 3d4(3G)4p 2H
561 271.0 561 860 −589 0.5 40 3d4 (3 D)4p 2P + 29 3d4(1S)4p 2P + 12 3d4(1D)4p 2P
561 677.0 561 998 −321 4.5 80 3d4 (1 I)4p 2H + 10 3d4(3G)4p 2H + 8 3d4(1G)4p 2H
561 985.0 561 596 389 2.5 47 3d4 (1 D)4p 2D + 19 3d4(3D)4p 2D + 17 3d4(1D)4p 2D
562 178.0 562 598 −420 3.5 62 3d4 (3 D)4p 2F + 10 3d4(3G)4p 2F + 7 3d4(1F)4p 2F
562 816.0 563 160 −344 2.5 49 3d4 (3 D)4p 2F + 19 3d4(1F)4p 2F + 16 3d4(3G)4p 2F
563 705.0 564 030 −325 1.5 25 3d4 (1 D)4p 2D + 24 3d4(1S)4p 2P + 12 3d4(3D)4p 2P
565 170.0 565 169 1 1.5 70 3d4 (3 D)4p 2D + 15 3d4(3F)4p 2D + 5 3d4(1D)4p 2D
565 670.0 565 238 432 2.5 35 3d4 (1 D)4p 2F + 20 3d4(3D)4p 2D + 16 3d4(3D)4p 2F
567 069.0 566 385 684 2.5 35 3d4 (3 D)4p 2D + 18 3d4(1D)4p 2F + 16 3d4(1D)4p 2D
567 778.0 566 943 835 3.5 49 3d4 (1 D)4p 2F + 28 3d4(1F)4p 2F + 12 3d4(1D)4p 2F
572 310.0 571 556 754 2.5 61 3d4 (1 F)4p 2F + 12 3d4(1G)4p 2F + 11 3d4(1D)4p 2F
573 402.0 573 064 338 0.5 68 3d4 (1 D)4p 2P + 14 3d4(1D)4p 2P + 9 3d4(1S)4p 2P
573 463.0 572 399 1064 3.5 46 3d4 (1 F)4p 2F + 23 3d4(1D)4p 2F + 10 3d4(1G)4p 2F
574 043.0 573 284 759 1.5 56 3d4 (1 D)4p 2P + 16 3d4(1S)4p 2P + 12 3d4(1G)4p 2P
575 709.0 575 410 299 3.5 84 3d4(1F)4p 2G + 6 3d4(1F)4p 2F
578 193.0 577 847 346 4.5 90 3d4(1F)4p 2G
582 101.0 582 247 −146 2.5 59 3d4(3F)4p 4F + 11 3d4(3P)4p 4D + 8 3d4(3F)4p 4F
582 434.0 582 473 −39 3.5 65 3d4(3F)4p 4F + 8 3d4(3F)4p 4D + 8 3d4(3F)4p 4F
582 632.0 582 763 −131 1.5 37 3d4(3F)4p 4F + 13 3d4(1F)4p 2D + 11 3d4(3P)4p 4D
583 223.0 583 285 −62 4.5 82 3d4(3F)4p 4F + 9 3d4(3F)4p 4F
583 496.0 583 891 −395 1.5 20 3d4(3P)4p 4P + 16 3d4(3P)4p 4D + 16 3d4(3F)4p 4F
583 853.0 583 914 −61 2.5 23 3d4(3P)4p 4D + 21 3d4(3F)4p 4F + 12 3d4(3P)4p 4D
584 627.0 584 697 −70 3.5 32 3d4(3P)4p 4D + 19 3d4(3F)4p 4D + 16 3d4(3F)4p 4F
586 361.0 586 509 −148 2.5 29 3d4(3F)4p 4G + 17 3d4(3P)4p 4P + 13 3d4(3F)4p 2F
587 400.0 587 450 −50 3.5 37 3d4(3F)4p 4G + 28 3d4(3F)4p 2F + 12 3d4(3F)4p 4G
588 525.0 588 525 0 2.5 26 3d4(1F)4p 2D + 19 3d4(3P)4p 2D + 13 3d4(3P)4p 2D
589 098.0 589 136 −38 3.5 39 3d4(3F)4p 2F + 31 3d4(3F)4p 4G + 10 3d4(3F)4p 4G
589 132.0 589 220 −88 1.5 33 3d4(1F)4p 2D + 21 3d4(3P)4p 2D + 17 3d4(3F)4p 2D
596 473.0 596 393 80 4.5 70 3d4(3F)4p 2G + 20 3d4(3F)4p 2G
596 790.0 597 023 −233 1.5 61 3d4(3P)4p 2P + 25 3d4(3P)4p 2P + 7 3d4(3D)4p 2P
597 774.0 597 560 214 3.5 72 3d4(3F)4p 2G + 22 3d4(3F)4p 2G
599 993.0 599 594 399 4.5 40 3d4(1G)4p 2H + 22 3d4(1G)4p 2G + 19 3d4(1G)4p 2H
600 555.0 600 479 76 3.5 51 3d4(1G)4p 2G + 31 3d4(1G)4p 2G + 7 3d4(1G)4p 2F
601 692.0 601 391 301 0.5 54 3d4(3P)4p 2S + 41 3d4(3P)4p 2S
603 569.0 603 112 457 4.5 37 3d4(1G)4p 2G + 23 3d4(1G)4p 2H + 22 3d4(1G)4p 2G
604 021.0 603 515 506 5.5 65 3d4(1G)4p 2H + 31 3d4(1G)4p 2H
604 655.0 604 594 61 3.5 53 3d4(1G)4p 2F + 16 3d4(1G)4p 2F + 8 3d4(1G)4p 2G
605 306.0 605 304 2 2.5 58 3d4(1G)4p 2F + 18 3d4(1G)4p 2F + 9 3d4(1D)4p 2F
608 598.0 608 701 −103 2.5 49 3d4(3F)4p 2D + 18 3d4(3F)4p 2D + 16 3d4(3P)4p 2D
609 072.0 609 176 −104 1.5 44 3d4(3F)4p 2D + 21 3d4(3P)4p 2D + 18 3d4(3F)4p 2D
634 888.0 634 813 75 3.5 72 3d4(1D)4p 2F + 19 3d4(1D)4p 2F + 5 3d4(1G)4p 2F

Notes. Energies are given in cm−1. (a) From van het Hof et al. (1990). (b)This work. (c)Only the first three components higher than or equal to 5% are given.

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