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Table A.8
Radial parameters (in cm−1) adopted for the calculations in Cu VII.
| Configuration | Parameter | HFR | Fitted | Ratio | Note(a) |
|---|---|---|---|---|---|
| Even parity | |||||
| 3d5 | Eav | 78 756 | 78 522 | ||
| F2(3d,3d) | 134 086 | 119 456 | 0.891 | ||
| F4(3d,3d) | 84 807 | 74 397 | 0.877 | ||
| α | 0 | 118 | |||
| β | 0 | −512 | |||
| ζ3d | 1176 | 1202 | 1.022 | ||
| Odd parity | |||||
| 3d44p | Eav | 553 653 | 554 223 | ||
| F2(3d,3d) | 139 722 | 123 787 | 0.886 | ||
| F4(3d,3d) | 88 617 | 78 219 | 0.883 | ||
| α | 0 | 123 | |||
| β | 0 | −380 | |||
| ζ3d | 1263 | 1121 | 0.888 | ||
| ζ4p | 2481 | 2647 | 1.067 | ||
| F2(3d,4p) | 35 417 | 34 983 | 0.988 | ||
| G1(3d,4p) | 11 725 | 11 199 | 0.955 | ||
| G3(3d,4p) | 11 316 | 11 458 | 1.013 | ||
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