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Table B.3
Equilibrium vapor pressure fit, .
No. | Reaction | A | B |
---|---|---|---|
Standard boundary condition | |||
1. | MgO(l) ⇌ Mg(g) + O(g) | 25.02 | 6.00 × 104 |
2. | MgO(l) ⇌ MgO(g) | 28.28 | 7.38 × 104 |
3. | Na2O(l) ⇌ 2 Na(g) + O(g) | 21.55 | 3.63 × 104 |
4. | SiO2(l) ⇌ Si(g) + 2 O(g) | 31.17 | 1.06 × 105 |
5. | SiO2(l) ⇌ SiO(g)+ O(g) | 31.21 | 6.72 × 104 |
6. | SiO2(l) ⇌ SiO2(g) | 27.98 | 6.65 × 104 |
7. | FeO(l) ⇌ Fe(g) + O(g) | 23.67 | 5.16 × 104 |
8. | FeO(l) ⇌ FeO(g) | 22.8 | 5.15 × 104 |
9. | K2O(l) ⇌ 2 K(g)+ O(g) | 16.22 | 4.11 × 104 |
10. | CaO(l) ⇌ Ca(g) + O(g) | 19.02 | 6.90 × 104 |
11. | CaO(l) ⇌ CaO(g) | 22.71 | 8.18 × 104 |
Modified boundary condition | |||
1. | MgO(l) ⇌ MgO(g) | 26.28 | 5.23 × 104 |
2. | NaO(l) ⇌ NaO(g) (a) | 23.12 | 5.23 × 104 |
3. | SiO2(l) ⇌ SiO2(g) | 26.74 | 5.23 × 104 |
4. | FeO(l) ⇌ FeO(g) | 25.52 | 5.23 × 104 |
5. | KO(l) ⇌ KO(g) (a) | 21.05 | 5.23 × 104 |
6. | CaO(l) ⇌ CaO(g) | 23.65 | 5.23 × 104 |
Notes. (a) For simplicity Na2 O and K2 O were replaced respectively by NaO and KO. This change has a small impact on the flowfield because their concentration is much smaller than the other components (see Fig. 9d).
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