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Table 5
Production and loss reactions of N(2D), C(1 D), and C(1 S) incorporated into the chemical network of the coupled-chemistry emission model.
| Reaction | Rate coefficient (†) | Reference |
|---|---|---|
| (cm3 molecule−1 s−1 or s−1) | ||
| hν + N2 → N(2D) + N | 3.0 × 10−7 | This work |
| hν + CN → N(2D) + C | 1.0 × 10−6 | This work |
| hν + CO → C(1D) + O | 7.6 × 10−8 | This work |
| hν + CN → C(1D) + N | 2.0 × 10−6 | This work |
| hν + CO2 → C(1D) + O | 1.5 × 10−10 | This work |
| hν + CO → C(1S) + O | 1.1 × 10−9 | This work |
| eph + N2 → N(2D) + N | Calculated | This work |
| eph + CN → N(2D) + C | Calculated | This work |
| eph + CO → C(1D) + O | Calculated | This work |
| eph + CN → C(1D) + N | Calculated | This work |
| eph + CO2 → C(1D) + O | Calculated | This work |
| N(2D) + H2O → N + H2O | 4.0 × 10−11 | Herron (1999) |
| N(2D) + CO2 → N + H2O | 3.6 × 10−13 | Herron (1999) |
| N(2D) + CO → N + H2O | 1.9 × 10−12 | Herron (1999) |
| N(2D) + O2 → N + O2 | 5.2 × 10−12 | Herron (1999) |
| N(2D) + N2 → N + N2 | 1.7 × 10−14 | Herron (1999) |
| N(2D) → N + hν5200 & 5198 Å | 2.78 × 10−5 | Wiese & Fuhr (2009) |
| C(1D) + H2O → C + H2O | 1.7 × 10−11 | Schofield (1979) |
| C(1D) + CO2 → C + H2O | 3.7 × 10−11 | Schofield (1979) |
| C(1D) + CO → C + H2O | 1.6 × 10−11 | Schofield (1979) |
| C(1D) + O2 → C + O2 | 2.6 × 10−11 | Schofield (1979) |
| C(1D) + N2 → C + N2 | 4.2 × 10−12 | Schofield (1979) |
| C(1D) → C + hν9824 & 9850 Å | 2.91 × 10−4 | Wiese & Fuhr (2009) |
| C(1S) + H2O → C + H2O | 1 × 10−16 | Schofield (1979) |
| C(1 S) + CO2 → C + H2O | 1 × 10−16 | Schofield (1979) |
| C(1 S) + CO → C + H2O | 6 × 10−14 | Schofield (1979) |
| C(1 S) + N2 → C + H2O | 3 × 10−15 | Schofield (1979) |
| C(1 S) → C + hν8727 Å | 0.6 | Wiese & Fuhr (2009) |
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