Open Access
Table 6
Energy profiles of reaction paths a and b in vacuum and in ice.
| Reactions | No ice involvement | Embedded in ice | ||
|---|---|---|---|---|
| ΔH# | ΔH | ΔH# | ΔH | |
| Reaction path a | ||||
| CH3CN + H• → CH3CHN• | 7.9 | −20.2 | 9.3 | −17.4 |
| CH3CHN• + H• → (E)-CH3CHNH | /(a) | −88.1 | /(a) | −88.1 |
(E)-CH3CHNH + H• → CH3CHNH |
4.1 | −34.1 | 4.7 | −32.3 |
CH3CHNH + H• → CH3CH2NH2 |
/(a) | −88.9 | /(a) | −89.1 |
| Reaction path b | ||||
| CH3NC + H• → (Z)-CH3NCH• | 2.9 | −22.6 | 3.8 | −20.3 |
| (Z)-CH3NCH• → (E)-CH3NCH• | 10.3 | −4.1 | 10.3 | −2.9 |
| (E)-CH3NCH• + H• → CH3NCH2 | /(a) | −94.8 | /(a) | −96.3 |
CH3NCH2 + H• → CH3NHCH |
4.5 | −34.9 | 5.0 | −34.1 |
CH3NHCH + H• → CH3NHCH3 |
/(a) | −89.8 | /(a) | −89.7 |
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