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Table B.1

Parameters of the non-detected molecular transitions.

Species Transition Frequency (a) Aij (a) Eu (a) ncrit (b)
(GHz) (s−1) (K) (cm−3)
      
CO-species

p-H2CO 112,9 − 120,12 215.97616 3.16 × 10−7 280 3.3 × 104
o-H2CO 91,8 − 91,9 216.56865 7.24 × 10−6 174 2.1 × 105
CH3OH 50,5 − 40,4 241.70022 6.03 × 10−5 48 1.7 × 106
CH3OH 50,5 − 4 241.79143 6.03 × 10−5 35 4.6 × 105
CH3OH 51,4 − 41,3 241.87907 6.03 × 10−5 56 1.5 × 107
CH3OH 51,4 − 4 241.91583 6.03 × 10−5 50 5.5 × 107

S-species

SO 12 − 21 236.45229 1.41 × 10−6 16 4.0 × 104 (c)
SO2 111,11 − 100,10 221.96522 1.15 × 10−4 60 8.6 × 106 (d)
SO2 123,9 − 122,10 237.06883 1.15 × 10−4 60 1.1 × 108 (d)
SO2 52,4 − 41,3 241.61580 8.51 × 10−5 24 9.4 × 106 (d)
SO2 140,14 − 131,13 244.25422 1.62 × 10−4 94 1.2 × 107 (d)
OCS J = 18−17 218.90336 3.02 × 10−5 100 8.2 × 105
OCS J = 19−18 231.06099 3.55 × 10−5 111 1.3 × 106
OCS J = 20−19 243.21804 4.17 × 10−5 123 3.5 × 105
p-H2S 22,0 − 21,1 216.71044 4.90 × 10−5 84 1.1 × 106
HCS 60,6 − 50,5 241.68929 1.20 × 10−5 41
HSC 61,6 − 51,5 239.05112 4.27 × 10−4 53
HSC 62,5 − 52,4 243.32134 4.17 × 10−4 94
HSC 60,6 − 50,5 243.36604 4.68 × 10−4 41
HSC 62,4 − 52,3 243.52763 4.17 × 10−4 94
H2CS 71,7 − 61,6 236.72702 1.91 × 10−4 59 5.5 × 106
H2CS 70,7 − 60,6 240.26687 2.04 × 10−4 46 2.0 × 107
H2CS 72,6 − 62,5 240.38205 1.91 × 10−4 99 4.0 × 106
H2CS 72,5 − 62,4 240.54907 1.91 × 10−4 99 6.4 × 106
H2 CS 71,6 − 61,5 244.04850 2.09 × 10−4 60 4.1 × 106

Carbon-chain species

N2 D+ 3−2 231.32186 7.08 × 10−4 22 2.1 × 106 (e)
H2 CN 30,3 − 20,2 219.85186 3.39 × 10−4 21
H2 CN 31,2 − 21,1 227.43700 3.39 × 10−4 34
c-C3 H2 82,6 − 81,7 (para) 218.44883 1.48 × 10−4 87 6.7 × 107
c-C3 H2 83,6 − 82,7 (ortho) 218.44944 1.48 × 10−4 87 3.2 × 108
c-C3 H2 32,1 − 21,2 (ortho) 244.22215 5.89 × 10−5 18 1.2 × 107
l-C3 H2 111,11 − 101,10 226.54857 1.07 × 10−3 79
l-C3 H2 110,11 − 100,10 228.60835 1.12 × 10−3 66
l-C3 H2 111,10 − 101,9 230.77801 1.15 × 10−3 80
C4 H N = 23−22, J = 47/2−45/2 218.83701 4.47 × 10−5 126
C4 H N = 23−22, J = 45/2−43/2 218.87537 4.47 × 10−5 126
C4 H N = 24−23, J = 49/2−47/2 228.34862 5.13 × 10−5 137
C4 H N = 24−23, J = 47/2−45/2 228.38696 5.13 × 10−5 137
C4 H N = 25−24, J = 51/2−49/2 237.85974 5.75 × 10−5 148
C4 H N = 25−24, J = 49/2−47/2 237.89806 5.75 × 10−5 148

Others

SiO J = 5−4 217.10498 5.25 × 10−4 31 2.2 × 107
HDO 31,2 − 22,1 225.89672 1.32 × 10−5 167 7.3 × 106
HDO 21,1 − 21,2 241.56155 1.17 × 10−5 95 9.6 × 105
HNCO 100,10 − 90,9 219.79827 1.48 × 10−4 58 4.4 × 108
HNCO 110,11 − 100,10 241.77403 1.95 × 10−4 70 2.3 × 107

Notes. (a) Values from the CDMS database (Müller et al. 2001). (b)Calculated values for a collisional temperature of 30 K and collisional rates from the Leiden Atomic and Molecular Database (LAMDA; Schöier et al. 2005). (c) For a collisional temperature of 60 K. (d)For a collisional temperature of 100 K. (e)Calculated for N2 H+. References.The collisional rates of specific species listed here and in Table 3 were taken from the following sources: CO isotopologues from Yang et al. (2010), H2 CO and H2 CS from Wiesenfeld & Faure (2013), CH3OH from Rabli & Flower (2010), DCO+ and N2 D+ from Flower (1999), DCN and DNC from Dumouchel et al. (2010), CS isotopologues and SO from Lique et al. (2006), SO2 from Balança et al. (2016), OCS from Green & Chapman (1978), H2S from Daniel et al. (2011), CN from Kalugina & Lique (2015), C3 H2 from Chandra & Kegel (2000), HC3N from Faure et al. (2016), SiO from Dayou & Balança (2006), HDO from Faure et al. (2012), and HNCO from Sahnoun et al. (2018).

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