Table 4
Assignments, measured line positions, and least-squares residuals for the analysed transitions of propargylamine.
| J′ |  |
 |
ν′ | F′ | J | Ka | Kc | ν | F | Observed | Obs.-calc. | Uncert. | Weight |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| (1) | (2) | (3) | (4) | (5) | (6) | (7) | (8) | (9) | (10) | (11) | (12) | (13) | (14) |
| 1 | 0 | 1 | 0 | 1 | 0 | 0 | 0 | 0 | 1 | 8754.9970 | 0.0087 | 0.005 | |
| 1 | 0 | 1 | 0 | 2 | 0 | 0 | 0 | 0 | 1 | 8755.8953 | 0.0026 | 0.005 | |
| 1 | 0 | 1 | 0 | 0 | 0 | 0 | 0 | 0 | 1 | 8757.2501 | 0.0008 | 0.005 | |
| 10 | 1 | 10 | 0 | * | 9 | 1 | 9 | 0 | * | 85170.851 | - 0.017 | 0.010 | |
| 10 | 0 | 10 | 0 | * | 9 | 0 | 9 | 0 | * | 86658.130 | 0.001 | 0.010 | |
| 10 | 2 | 9 | 0 | * | 9 | 2 | 8 | 0 | * | 87409.619 | - 0.008 | 0.015 | |
| 10 | 7 | 3 | 0 | 10 | 9 | 7 | 2 | 0 | 9 | 87626.025 | - 0.021 | 0.020 | 0.50 |
| 10 | 7 | 4 | 0 | 10 | 9 | 7 | 3 | 0 | 9 | 87626.025 | - 0.021 | 0.020 | 0.50 |
| 10 | 7 | 3 | 0 | 11 | 9 | 7 | 2 | 0 | 10 | 87626.390 | 0.026 | 0.020 | 0.26 |
| 10 | 7 | 4 | 0 | 11 | 9 | 7 | 3 | 0 | 10 | 87626.390 | 0.026 | 0.020 | 0.26 |
| 10 | 7 | 3 | 0 | 9 | 9 | 7 | 2 | 0 | 8 | 87626.390 | - 0.014 | 0.020 | 0.24 |
| 10 | 7 | 4 | 0 | 9 | 9 | 7 | 3 | 0 | 8 | 87626.390 | - 0.014 | 0.020 | 0.24 |
| 64 | 4 | 61 | 0 | * | 63 | 4 | 60 | 0 | * | 553940.631 | - 0.004 | 0.020 | |
| 65 | 2 | 64 | 0 | * | 64 | 1 | 63 | 0 | * | 549064.979 | - 0.024 | 0.020 | |
| 9 | 1 | 9 | 1 | * | 8 | 1 | 8 | 1 | * | 76816.540 | 0.007 | 0.015 | |
| 9 | 0 | 9 | 1 | * | 8 | 0 | 8 | 1 | * | 78276.573 | 0.003 | 0.015 | |
| 9 | 2 | 8 | 1 | * | 8 | 2 | 7 | 1 | * | 78863.436 | 0.007 | 0.020 | |
| 10 | 7 | 3 | 1 | 10 | 9 | 7 | 2 | 1 | 9 | 87814.069 | - 0.011 | 0.020 | 0.50 |
| 10 | 7 | 4 | 1 | 10 | 9 | 7 | 3 | 1 | 9 | 87814.069 | - 0.011 | 0.020 | 0.50 |
| 10 | 7 | 3 | 1 | 11 | 9 | 7 | 2 | 1 | 10 | 87814.429 | 0.031 | 0.020 | 0.26 |
| 10 | 7 | 4 | 1 | 11 | 9 | 7 | 3 | 1 | 10 | 87814.429 | 0.031 | 0.020 | 0.26 |
| 10 | 7 | 3 | 1 | 9 | 9 | 7 | 2 | 1 | 8 | 87814.429 | - 0.008 | 0.020 | 0.24 |
| 10 | 7 | 4 | 1 | 9 | 9 | 7 | 3 | 1 | 8 | 87814.429 | - 0.008 | 0.020 | 0.24 |
| 34 | 6 | 29 | 1 | * | 33 | 6 | 28 | 1 | * | 299155.896 | 0.002 | 0.020 | |
| 34 | 6 | 28 | 1 | * | 33 | 6 | 27 | 1 | * | 299171.746 | - 0.003 | 0.020 | |
| 39 | 1 | 39 | 1 | * | 38 | 1 | 38 | 1 | * | 327901.796 | - 0.001 | 0.020 | |
| 39 | 0 | 39 | 1 | * | 38 | 0 | 38 | 1 | * | 327918.765 | - 0.016 | 0.020 | |
| 9 | 1 | 9 | 2 | * | 8 | 1 | 8 | 2 | * | 76774.271 | 0.006 | 0.015 | |
| 9 | 0 | 9 | 2 | * | 8 | 0 | 8 | 2 | * | 78241.811 | 0.002 | 0.015 | |
| 9 | 2 | 8 | 2 | * | 8 | 2 | 7 | 2 | * | 78799.091 | - 0.007 | 0.020 | |
| 10 | 7 | 3 | 2 | 10 | 9 | 7 | 2 | 2 | 9 | 87741.521 | - 0.018 | 0.020 | 0.50 |
| 10 | 7 | 4 | 2 | 10 | 9 | 7 | 3 | 2 | 9 | 87741.521 | - 0.018 | 0.020 | 0.50 |
| 10 | 7 | 3 | 2 | 11 | 9 | 7 | 2 | 2 | 10 | 87741.859 | 0.022 | 0.020 | 0.26 |
| 10 | 7 | 4 | 2 | 11 | 9 | 7 | 3 | 2 | 10 | 87741.859 | 0.022 | 0.020 | 0.26 |
| 10 | 7 | 3 | 2 | 9 | 9 | 7 | 2 | 2 | 8 | 87741.859 | - 0.015 | 0.020 | 0.24 |
| 10 | 7 | 4 | 2 | 9 | 9 | 7 | 3 | 2 | 8 | 87741.859 | - 0.015 | 0.020 | 0.24 |
| 34 | 6 | 29 | 2 | * | 33 | 6 | 28 | 2 | * | 298862.541 | 0.004 | 0.020 | |
| 34 | 6 | 28 | 2 | * | 33 | 6 | 27 | 2 | * | 298877.335 | - 0.002 | 0.020 | |
| 42 | 0 | 42 | 2 | * | 41 | 1 | 41 | 2 | * | 352684.374 | 0.013 | 0.020 | |
| 10 | 1 | 10 | 3 | * | 9 | 1 | 9 | 3 | * | 85262.099 | 0.000 | 0.010 | |
| 10 | 2 | 9 | 3 | * | 9 | 2 | 8 | 3 | * | 87489.609 | - 0.002 | 0.015 | |
| 10 | 7 | 3 | 3 | 10 | 9 | 7 | 2 | 3 | 9 | 87704.679 | - 0.020 | 0.020 | 0.50 |
| 10 | 7 | 4 | 3 | 10 | 9 | 7 | 3 | 3 | 9 | 87704.679 | - 0.020 | 0.020 | 0.50 |
| 10 | 7 | 3 | 3 | 11 | 9 | 7 | 2 | 3 | 10 | 87705.039 | 0.022 | 0.020 | 0.26 |
| 10 | 7 | 4 | 3 | 11 | 9 | 7 | 3 | 3 | 10 | 87705.039 | 0.022 | 0.020 | 0.26 |
| 10 | 7 | 3 | 3 | 9 | 9 | 7 | 2 | 3 | 8 | 87705.039 | - 0.018 | 0.020 | 0.24 |
| 10 | 7 | 4 | 3 | 9 | 9 | 7 | 3 | 3 | 8 | 87705.039 | - 0.018 | 0.020 | 0.24 |
| 34 | 6 | 29 | 3 | * | 33 | 6 | 28 | 3 | * | 298722.618 | - 0.010 | 0.020 | |
| 34 | 6 | 28 | 3 | * | 33 | 6 | 27 | 3 | * | 298737.942 | 0.029 | 0.020 | |
| 30 | 0 | 30 | 3 | * | 29 | 1 | 29 | 3 | * | 252480.569 | - 0.022 | 0.020 | |
Notes. Column content: (1−3) upper state rotational quantum numbers J′,
,
; (4) upper state vibrational label; (5) upper state total quantum number F′; (6−8) lower state rotational quantum numbers J, Ka, Kc ; (9) lower state vibrational label; (10) lower state total quantum number F; (11) measured line frequency (MHz); (12) least-squares residual (MHz); (13) assumed uncertainty (MHz); (14) relative weights for blended transitions. Asterisks in Cols. (5) and (10) indicate completely unresolved hyperfine structure. Vibrational labels are 0 for ground state, 1 for v13 = 1, 2 for v21 = 1, and 3 for v20 = 1. The full table is available at the CDS.