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Table A.21
Term values (cm−1) of the E1Π(v′ = 0) e- and f-parity levels for six CO isotopologues.
| E1Π(v′ = 0) | ||||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 12C16O | 12C17O | 12C18O | 13C16O | 13C17O | 13C18O | |||||||||||||
| J′ | e-par. (R&P) | f-par. (Q) | Λd | e-par. (R&P) | f-par. (Q) | Λd | e-par. (R&P) | f-par. (Q) | Λd | e-par. (R&P) | f-par. (Q) | Λd | e-par. (R&P) | f-par. (Q) | Λd | e-par. (R&P) | f-par. (Q) | Λd |
| 1 | 92933.878 (30) | 92933.833a | 0.045 | 92933.575 (21) | 92933.462e | 0.113 | 92933.325 (27) | 92933.247e | 0.077 | 92933.530 (23) | 92933.480a | 0.050 | 92933.010 (−19) | 92932.900a | 0.110 | |||
| 2 | 92941.744 (55) | 92941.644a | 0.100 | 92941.207 (19) | 92941.075e | 0.132 | 92940.798 (55) | 92940.692e | 0.106 | 92941.048 (68) | 92940.946a | 0.102 | 92940.821 | 92940.163 (26) | 92939.994a | 0.168 | ||
| 3 | 92953.499 (12) | 92953.360a | 0.139 | 92952.673 (40) | 92952.493e | 0.180 | 92952.000 (17) | 92951.858e | 0.142 | 92952.276 (27) | 92952.147a | 0.129 | 92951.820 | 92950.703 (22) | 92950.637a | 0.066 | ||
| 4 | 92969.209 (17) | 92968.980a | 0.229 | 92968.042 (8) | 92967.718e | 0.324 | 92966.964 (3) | 92966.743e | 0.221 | 92967.309 (−13) | 92967.080a | 0.229 | 92966.508 | 92964.762 (*) | 92964.828a | −0.066 | ||
| 5 | 92988.865 (−1) | 92988.502a | 0.363 | 92987.156 (1) | 92986.750e | 0.406 | 92985.655 (−2) | 92985.343e | 0.311 | 92986.065 (3) | 92985.744a | 0.321 | 92984.470 (*) | 92982.520 (*) | 92982.563a | −0.043 | ||
| 6 | 93012.438 (−6) | 93011.929a | 0.508 | 93010.137 (2) | 93009.589e | 0.547 | 93008.091 (0) | 93007.656e | 0.435 | 93008.610 (0) | 93008.141a | 0.469 | 93006.594 (*) | 93004.115 (125) | 93003.844a | 0.271 | ||
| 7 | 93039.915 (4) | 93039.258a | 0.657 | 93036.912 (19) | 93036.235e | 0.677 | 93034.290 (−3) | 93033.675e | 0.616 | 93034.867 (−3) | 93034.267a | 0.600 | 93031.813 (121) | 93029.077 (*) | 93028.671a | 0.406 | ||
| 8 | 93071.339 (3) | 93070.488a | 0.851 | 93067.553 (1) | 93066.689e | 0.863 | 93064.209 (5) | 93063.409e | 0.800 | 93064.908 (−7) | 93064.068 | 0.840 | 93061.093 (−56) | 93057.680 (66) | 93057.006 | 0.674 | ||
| 9 | 93106.692 (3) | 93105.634 | 1.058 | 93102.005 (1) | 93100.951 | 1.054 | 93097.850 (0) | 93096.859 | 0.991 | 93098.680 (4) | 93097.699 | 0.981 | 93093.972 (−36) | 93089.733 (76) | 93088.945 | 0.788 | ||
| 10 | 93145.946 (−6) | 93144.672 | 1.274 | 93140.279 (−15) | 93138.997 | 1.282 | 93135.249 (−9) | 93134.063 | 1.186 | 93136.223 (−8) | 93135.052 | 1.171 | 93130.487 (−12) | 93125.443 (31) | 93124.392 | 1.051 | ||
| 11 | 93189.164 (−1) | 93187.609 | 1.555 | 93182.357 (−10) | 93180.817 | 1.540 | 93176.368 (−7) | 93174.965 | 1.403 | 93177.494 (−4) | 93176.072 | 1.422 | 93170.667 (−4) | 93164.667 (16) | 93163.355 | 1.312 | ||
| 12 | 93236.240 (−19) | 93234.382 | 1.858 | 93228.270 (−11) | 93226.498 | 1.773 | 93221.214 (−11) | 93219.526 | 1.688 | 93222.524 (20) | 93220.805 | 1.719 | 93214.514 (12) | 93207.449 (19) | 93205.926 | 1.523 | ||
| 13 | 93287.268 (−7) | 93285.114 | 2.154 | 93278.016 (−3) | 93275.929 | 2.087 | 93269.803 (−2) | 93267.830 | 1.973 | 93271.289 (−14) | 93269.325 | 1.964 | 93261.994 (−4) | 93253.743 (−3) | 93252.010 | 1.733 | ||
| 14 | 93342.198 (5) | 93339.694 | 2.504 | 93331.572 (−1) | 93329.181 | 2.391 | 93322.106 (−7) | 93319.833 | 2.272 | 93323.807 (0) | 93321.522 | 2.285 | 93313.108 (1) | 93303.675 (19) | 93301.595 | 2.079 | ||
| 15 | 93401.050 (−4) | 93398.212 | 2.839 | 93388.904 (2) | 93386.198 | 2.707 | 93378.155 (11) | 93375.560 | 2.595 | 93380.058 (8) | 93377.441 | 2.617 | 93367.880 (3) | 93357.121 (22) | 93354.773 | 2.348 | ||
| 16 | 93463.838 (−1) | 93460.682 | 3.156 | 93450.064 (−2) | 93446.804 | 3.260 | 93437.905 (1) | 93434.991 | 2.914 | 93440.065 (−13) | 93437.142 | 2.922 | 93426.266 (−2) | 93423.571 | 2.695 | 93414.130 (−1) | 93411.338 | 2.793 |
| 17 | 93530.484 (−5) | 93526.855 | 3.629 | 93515.058 (−3) | 93511.579 | 3.479 | 93501.388 (4) | 93498.062 | 3.326 | 93503.789 (27) | 93500.410 | 3.379 | 93488.318 (−1) | 93485.311 | 3.007 | 93474.644 (6) | 93471.663 | 2.980 |
| 18 | 93601.072 (−3) | 93597.021 | 4.050 | 93583.842 (−2) | 93579.962 | 3.880 | 93568.577 (−9) | 93564.887 | 3.690 | 93571.227 (7) | 93567.511 | 3.715 | 93553.973 (4) | 93550.600 | 3.373 | 93538.743 (15) | 93535.404 | 3.340 |
| 19 | 93675.514 (15) | 93671.007 | 4.507 | 93656.435 (−1) | 93652.174 | 4.261 | 93639.506 (3) | 93635.401 | 4.105 | 93642.412 (23) | 93638.282 | 4.130 | 93623.295 (8) | 93606.371 (26) | 93602.603 | 3.768 | ||
| 20 | 93753.899 (18) | 93748.983 | 4.916 | 93732.822 (−8) | 93728.049 | 4.773 | 93714.135 (1) | 93709.645 | 4.490 | 93717.314 (23) | 93712.853 | 4.461 | 93696.218 (2) | 93677.553 (11) | 93673.387 | 4.166 | ||
| 21 | 93836.178 (−2) | 93830.681 | 5.496 | 93813.013 (12) | 93807.799 | 5.214 | 93792.503 (−4) | 93787.501 | 5.002 | 93795.989 (22) | 93790.953 | 5.036 | 93772.782 (−16) | 93752.286 (27) | 93747.784 | 4.503 | ||
| 22 | 93922.337 (6) | 93916.344 | 5.993 | 93896.992 (21) | 93891.273 | 5.719 | 93874.551 (−8) | 93869.101 | 5.450 | 93878.345 (28) | 93872.742 | 5.603 | 93852.983 (−22) | 93830.541 (−10) | 93825.568 | 4.973 | ||
| 23 | 94012.379 (−13) | 94005.944 | 6.435 | 93984.762 (3) | 93978.765 | 5.997 | 93960.305 (−11) | 93954.467 | 5.838 | 93964.425 (−5) | 93958.408 | 6.018 | 93936.765 | 93912.329 (−17) | 93907.037 | 5.292 | ||
| 24 | 94106.331 (−14) | 94099.250 | 7.081 | 94076.360 (−33) | 94069.544 | 6.816 | 94049.774 (−3) | 94043.304 | 6.470 | 94054.231 (8) | 94047.766 | 6.465 | 94024.193 | 93997.645 (−21) | 93991.966 | 5.679 | ||
| 25 | 94204.145 (1) | 94196.467 | 7.678 | 94171.633 (21) | 94164.280 | 7.353 | 94142.903 (−5) | 94135.934 | 6.969 | 94147.735 (1) | 94140.896 | 6.839 | 94115.203 | 94086.502 (6) | 94080.358 | 6.144 | ||
| 26 | 94305.826 (−5) | 94297.544 | 8.282 | 94270.495 (*) | 94239.766 (−1) | 94232.325 | 7.441 | 94244.954 (6) | 94209.849 | 94178.841 (8) | 94172.509 | 6.332 | ||||||
| 27 | 94411.406 (9) | 94402.485 | 8.921 | 94373.422 (*) | 94364.698 | 8.723 | 94340.385 (−8) | 94332.024 | 8.361 | 94345.979 (0) | 94308.197 | 94274.798 (14) | ||||||
| 28 | 94520.866 (2) | 94511.144 | 9.722 | 94480.069 (*) | 94444.550 (0) | 94435.010 | 9.540 | 94450.537 (5) | 94374.230 (−6) | |||||||||
| 29 | 94634.154 (8) | 94623.932 | 10.222 | 94552.491 (−4) | 94541.928 | 10.563 | 94558.855 (0) | 94477.134 (6) | ||||||||||
| 30 | 94751.320 (−8) | 94664.061(−7) | 94652.570 | 11.491 | 94670.867 (14) | 94583.607 (6) | ||||||||||||
| 31 | 94872.072 (*) | 94779.347 (3) | 94766.874 | 12.473 | 94786.606 (−2) | 94693.532 (−1) | ||||||||||||
| 32 | 94996.743 (*) | 94898.307 (−17) | 94905.981 (12) | 94806.976 (11) | ||||||||||||||
| 33 | 95125.965 | 95020.894 (33) | 95029.057 (−2) | 94923.983 (58) | ||||||||||||||
| 34 | 95258.538 | 95147.182 | 95155.825 (−2) | 95044.372 (0) | ||||||||||||||
| 35 | 95395.000 | 95277.045 | 95286.218 (11) | 95168.285 (−8) | ||||||||||||||
| 36 | 95420.319 (38) | 95295.635 (−60) | ||||||||||||||||
| 37 | 95558.078 (−2) | 95426.758 (91) | ||||||||||||||||
| 38 | 95699.410 (58) | 95561.129 (54) | ||||||||||||||||
| 39 | 95844.488 | 95698.962 (93) | ||||||||||||||||
| 40 | 95993.041 | 95840.259 | ||||||||||||||||
| 41 | 96144.880 | 95984.375 | ||||||||||||||||
Notes. The δP value in parentheses (in units of the least significant digit) corresponds to the wavenumber correction applied to TVP and TVR. There is no value when the term value is derived from a single transition, either R or P. An asterisk indicates when both R- and P-branches are present at high J′, either the potential presence of a perturbing state or that one of the lines shows a larger uncertainty than the other (see also Sect. 2.2.2). Each third column is the Λ -type doubling (cm−1) of the 1 Π state: Λ d = TVR&P–TVQ. (a) Data from Cacciani & Ubachs (2004). (*) Data calculated from the e-parity levels.
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