Table A.1
Measured transition wavelengths and wavenumbers of the B1Σ+(v′ = 0)–X1Σ+(v′′ = 0) band for 12C16O, 12 C17O, and 12 C18O.
B1Σ+(v′ = 0)–X1Σ+(v′′ = 0) | |||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
12C16O | 12C17O | 12C18O | |||||||||||||
J′′ | Rms (nm) | Pms (nm) | Rms (cm−1) | Pms (cm−1) | δP | Rms (nm) | Pms (nm) | Rms (cm−1) | Pms (cm−1) | δP | Rms (nm) | Pms (nm) | Rms (cm−1) | Pms (cm−1) | δP |
0 | 115.04826 | 86920.042 | 115.04802 | 86920.225 | 115.04772 | 86920.452 | |||||||||
1 | 115.04305 | 115.05849 | 86923.984 | 86912.315 | 6 | 115.04289 | 115.05805 | 86924.101 | 86912.649 | −17 | 115.04274 | 115.05747 | 86924.214 | 86913.086 | 10 |
2 | 115.03774 | 115.06355 | 86927.998 | 86908.496 | 1 | 115.03770 | 115.06286 | 86928.023 | 86909.015 | −17 | 115.03766 | 115.06229 | 86928.053 | 86909.445 | 16 |
3 | 115.03240 | 115.06850 | 86932.031 | 86904.758 | 9 | 115.03245 | 115.06765 | 86931.990 | 86905.397 | 5 | 115.03258 | 115.06702 | 86931.892 | 86905.873 | 26 |
4 | 115.02696 | 115.07339 | 86936.140 | 86901.066 | 9 | 115.02708 | 115.07244 | 86936.048 | 86901.779 | 20 | 115.02741 | 115.07166 | 86935.799 | 86902.368 | 3 |
5 | 115.02144 | 115.07823 | 86940.314 | 86897.411 | 0 | 115.02189 | 115.07715 | 86939.971 | 86898.222 | 51 | 115.02224 | 115.07621 | 86939.706 | 86898.932 | 14 |
6 | 115.01590 | 115.08294 | 86944.501 | 86893.853 | 6 | 115.01641 | 115.08178 | 86944.113 | 86894.726 | 0 | 115.01689 | 115.08076 | 86943.750 | 86895.497 | −4 |
7 | 115.01030 | 115.08760 | 86948.737 | 86890.331 | 3 | 115.01098 | 115.08637 | 86948.218 | 86891.261 | 9 | 115.01156 | 115.08523 | 86947.780 | 86892.121 | 9 |
8 | 115.00463 | 115.09223 | 86953.021 | 86886.840 | 4 | 115.00540 | 115.09083 | 86952.437 | 86887.897 | −5 | 115.00615 | 115.08960 | 86951.870 | 86888.822 | −15 |
9 | 114.99887 | 115.09679 | 86957.379 | 86883.393 | −12 | 114.99982 | 115.09527 | 86956.656 | 86884.542 | 16 | 115.00067 | 115.09389 | 86956.013 | 86885.583 | −11 |
10 | 114.99304 | 115.10125 | 86961.787 | 86880.030 | −8 | 114.99412 | 115.09965 | 86960.966 | 86881.235 | 11 | 114.99514 | 115.09817 | 86960.195 | 86882.353 | −9 |
11 | 114.98716 | 115.10565 | 86966.228 | 86876.707 | 2 | 114.98844 | 115.10396 | 86965.262 | 86877.982 | 17 | 114.98953 | 115.10237 | 86964.437 | 86879.182 | −21 |
12 | 114.98121 | 115.11000 | 86970.730 | 86873.423 | 3 | 114.98244 | 115.10818 | 86969.800 | 86874.802 | −5 | 114.98382 | 115.10648 | 86968.756 | 86876.080 | −1 |
13 | 114.97524 | 115.11428 | 86975.249 | 86870.193 | 9 | 114.97678 | 115.11233 | 86974.081 | 86871.665 | 63 | 114.97812 | 115.11059 | 86973.067 | 86872.978 | 20 |
14 | 114.96914 | 115.11849 | 86979.863 | 86867.016 | −8 | 114.97085 | 115.11640 | 86978.566 | 86868.594 | −17 | 114.97233 | 115.11460 | 86977.447 | 86869.952 | 10 |
15 | 114.96304 | 115.12261 | 86984.475 | 86863.908 | −2 | 114.96487 | 115.12041 | 86983.090 | 86865.568 | −2 | 114.96654 | 115.11853 | 86981.828 | 86866.986 | 2 |
16 | 114.95686 | 115.12666 | 86989.151 | 86860.854 | 1 | 114.95884 | 115.12440 | 86987.654 | 86862.558 | −1 | 114.96062 | 115.12237 | 86986.307 | 86864.089 | −1 |
17 | 114.95060 | 115.13070 | 86993.892 | 86857.806 | −17 | 114.95278 | 115.12830 | 86992.241 | 86859.620 | 6 | 114.95465 | 115.12622 | 86990.824 | 86861.184 | −23 |
18 | 114.94430 | 115.13459 | 86998.662 | 86854.872 | −7 | 114.94661 | 115.13215 | 86996.913 | 86856.714 | −9 | 114.94864 | 115.12988 | 86995.373 | 86858.423 | 10 |
19 | 114.93787 | 115.13846 | 87003.527 | 86851.949 | −10 | 114.94040 | 115.13590 | 87001.608 | 86853.881 | −23 | 114.94258 | 115.13363 | 86999.959 | 86855.594 | −4 |
20 | 114.93149 | 115.14226 | 87008.359 | 86849.088 | 9 | 114.93414 | 115.13954 | 87006.349 | 86851.136 | 2 | 114.93644 | 115.13721 | 87004.607 | 86852.893 | −3 |
21 | 114.92501 | 115.14597 | 87013.265 | 86846.284 | −8 | 114.92781 | 115.14325 | 87011.143 | 86848.341 | −5 | 114.93027 | 115.14077 | 87009.278 | 86850.208 | −3 |
22 | 114.91843 | 115.14963 | 87018.241 | 86843.524 | −7 | 114.92137 | 115.14680 | 87016.015 | 86845.662 | −8 | 114.92399 | 115.14424 | 87014.032 | 86847.590 | 0 |
23 | 114.91184 | 115.15323 | 87023.231 | 86840.809 | 3 | 114.91489 | 115.15028 | 87020.926 | 86843.033 | 51 | 114.91774 | 115.14768 | 87018.765 | 86844.996 | −9 |
24 | 114.90519 | 115.15676 | 87028.271 | 86838.153 | −3 | 114.90849 | 115.15382 | 87025.775 | 86840.364 | 114.91137 | 115.15097 | 87023.589 | 86842.514 | −18 | |
25 | 114.89849 | 115.16021 | 87033.342 | 86835.550 | −2 | 114.90196 | 87030.716 | 114.90494 | 115.15428 | 87028.458 | 86840.018 | −9 | |||
26 | 114.89170 | 115.16360 | 87038.490 | 86832.989 | −6 | 114.89540 | 87035.688 | 114.89851 | 115.15751 | 87033.329 | 86837.583 | 16 | |||
27 | 114.88486 | 115.16694 | 87043.673 | 86830.477 | 2 | 114.89198 | 115.16071 | 87038.275 | 86835.170 | −1 | |||||
28 | 114.87798 | 115.17019 | 87048.886 | 86828.026 | 6 | 114.88544 | 115.16379 | 87043.230 | 86832.847 | 1 | |||||
29 | 114.87110 | 115.17337 | 87054.100 | 86825.627 | 9 | 114.87886 | 115.16681 | 87048.216 | 86830.570 | 18 | |||||
30 | 114.86409 | 115.17650 | 87059.409 | 86823.267 | −1 | 114.87215 | 115.16985 | 87053.300 | 86828.278 | −10 | |||||
31 | 114.85707 | 115.17958 | 87064.733 | 86820.943 | 6 | 114.86552 | 115.17272 | 87058.325 | 86826.115 | 99 | |||||
32 | 114.84998 | 115.18257 | 87070.105 | 86818.688 | 0 | 114.85872 | 115.17581 | 87063.479 | 86823.785 | ||||||
33 | 114.84285 | 115.18550 | 87075.509 | 86816.485 | |||||||||||
34 | 114.83569 | 87080.944 | |||||||||||||
35 | 114.82841 | 87086.459 | |||||||||||||
36 | 114.82121 | 87091.926 |
Notes. Column description (refer also to Sect. 2.2) for each isotopologue. Col. 1: J′′ . Cols. 2 and 3: Rc and Pc calibrated wavelengths. Cols. 4 and 5: Rc and Pc calibrated wavenumbers. Col. 6: δP wavenumber corrections applied to TVP in units of the least significant digit (− δP is applied to TVR). No value indicates the absence of one of the branches, either R or P. An asterisk indicates when both R- and P-branches are present at high J′, either the potential presence of a perturbing state or that one of the lines shows a larger uncertainty than the other.
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