RAIR spectrum of the reaction, CH4 + H + O2, on a 10 K substrate surface after 12 hours (exp. 1.0). The relative column density of CH4 :CH3OH is 100:1, and the relative column density of H2O:CH3OH is 100:4. Spectra of the resulting species are shown (see Table 2), most noticeably a weaker band around 1000 cm−1 (inset) highlighting the C–O stretch of the CH3OH feature.
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