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Table A.14

Comparison between available experimental and calculated energy levels in I vi.

E exp a E calc b ΔE J Leading components (in %) in LS couplingc

Even parity
0.0 0 0 0 98 5s21S
200 084.8 199 954 131 0 91 5p23P + 9 5p21S
208 474.5 208 663 188 1 100 5p23P
209 431.7 209 483 51 2 54 5p21D + 32 5p23P + 13 5s5d 1D
221 983.8 221 854 130 2 67 5p23P + 23 5p21D + 10 5s5d 1D
245 658.5 245 671 12 0 87 5p21S + 9 5p23P
251 816.9 251 813 4 1 99 5s5d 3D
252 540.3 252 548 8 2 99 5s5d 3D
253 751.8 253 749 3 3 99 5s5d 3D
270 094.7 270 103 8 2 73 5s5d 1D + 21 5p21D
296 253.4 296 253 0 1 100 5s6s 3S
302 858.0 302 858 0 0 100 5s6s 1S
416 535.0 416 535 0 1 100 5s7s 3S
418 707.0 418 707 0 0 100 5s7s 1S
Odd parity
85 665.6 85 709 43 0 100 5s5p 3P
89 261.7 89 206 56 1 97 5s5p 3P
99 685.4 99 694 9 2 100 5s5p 3P
127 423.8 127 425 1 1 95 5s5p 1P
335 737.6 335 685 53 0 98 5s6p 3P
336 197.2 336 250 53 1 80 5s6p 3P + 18 5s6p 1P
340 462.4 340 471 9 2 97 5s6p 3P
341 729.0 341 715 14 1 78 5s6p 1P + 18 5s6p 3P
347 472.0 347 424 48 2 79 5p5d 3F + 17 5p5d 1D
353 652.0 353 515 137 3 89 5p5d 3F + 6 5p5d 3D
356 797.0 356 664 133 2 52 5p5d 1D + 21 5p5d 3P + 14 5p5d 3D
361 780.0 362 087 307 1 71 5p5d 3D + 20 5p5d 3P + 7 5p5d 1P
362 500.0 362 198 302 4 97 5p5d 3F
366 578.0 366 655 77 2 38 5p5d 3D + 28 5p5d 1D + 25 5p5d 3P
371 695.0 371 764 69 3 89 5p5d 3D + 7 5p5d 3F
373 009.0 373 262 253 0 98 5p5d 3P
373 131.0 373 343 212 1 75 5p5d 3P + 23 5p5d 3D
373 476.0 373 534 58 2 51 5p5d 3P + 45 5p5d 3D
387 975.0 387 436 539 3 62 5p5d 1F + 29 5s5f 1F
402 785.0 402 622 163 0 98 5p6s 3P
404 136.0 404 309 173 1 78 5p6s 3P + 17 5p6s 1P
417 041.0 417 074 33 2 98 5p6s 3P
419 603.0 419 555 48 1 61 5p6s 1P + 18 5p6s 3P + 16 5s7p 1P

Notes. Energies are given in cm-1.

(b)

This work.

(c)

Only the first three components larger than 5% are given.

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