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Table 2
Photodissociated molecules, absorbed photons, and photodissociation yield (in molecules per absorbed photon) at each irradiation interval for methanol and fully deuterated methanol at 8 K (experiments 1 and 7 in Table 1).
Irrad. | Photodiss. | Absorbed | Photodiss. |
time | molecules | photons | yield |
min. | [× 1016 molec./cm2] | [× 1016 phot./cm2] | [molec./abs. phot.] |
|
|||
CH3OH | |||
5 | 2.8 | 5.3 | 0.5 |
10 | 3.0 | 10.4 | 0.3 |
15 | 2.4 | 16.1 | 0.2 |
30 | 2.1 | 32.8 | 0.06 |
60 | 1.5 | 67.5 | 0.02 |
120 | 0.3 | 136.1 | 0.002 |
|
|||
CD3OD | |||
5 | 4.3 | 4.9 | 0.8 |
10 | 3.8 | 10.1 | 0.4 |
15 | 2.7 | 15.9 | 0.2 |
30 | 1.6 | 33.4 | 0.05 |
60 | 1.2 | 68.1 | 0.02 |
120 | 0.4 | 135.4 | 0.003 |
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