Table A.1
Values of ΔE for the different reactions computed with the assumption that ΔEe = 101 meV.
Reaction | ΔE (meV) | ΔE (K) | ||
|
||||
N+ (3P0) + H2 ( J = 0 ) | → | NH+ + H | 18.53 | 215.0 |
N+ (3P0) + H2 ( J = 1 ) | → | NH+ + H | 3.84 | 44.6 |
N+ (3P1) + H2 ( J = 0 ) | → | NH+ + H | 12.49 | 144.9 |
N+ (3P1) + H2 ( J = 1 ) | → | NH+ + H | −2.20 | |
N+ (3P2) + H2 ( J = 0 ) | → | NH+ + H | 2.31 | 26.8 |
N+ (3P2) + H2 ( J = 1 ) | → | NH+ + H | −12.38 | |
N+ (3P0) + HD ( J = 0 ) | → | ND+ + H | 4.21 | 48.9 |
N+ (3P0) + HD ( J = 0 ) | → | NH+ + D | 54.06 | 627.3 |
N+ (3P1) + HD ( J = 0 ) | → | ND+ + H | −1.83 | |
N+ (3P1) + HD ( J = 0 ) | → | NH+ + D | 48.02 | 557.2 |
|
||||
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→ | NH+ + H | 18.2 | 211.2 |
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→ | NH+ + H | 3.51 | 40.7 |
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→ | ![]() |
3.74 | 43.4 |
Notes. A minus sign corresponds to an exothermic reaction. The ZPE of H2 and HD are respectively 2170.2 and 1883.6 cm-1, i.e. 269.07 and 233.54 meV, whereas those of NH+ (15NH+) and ND+ (15ND+) are respectively 1505 (1502.4) and 1103 (1099.2) cm-1, corresponding to 186.60 (186.27) and 136.75 meV. The J = 1 level of H2 has an energy of 14.69 meV.
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