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Table A.5

Line list of rotational transitions for CH3NCO compiled form experimental frequencies (MHz) for line sequences assigned on the basis of continuity from the assignment reached for J″ ≤ 3.

(a) νb = 0, m = 0 (ground state), Evib = 0 cm-1.
Ka = 0 1L 1U 2L 2U 3L 3U
J′ J′′
1 0 8 671.410b
2 1 17 342.500 17 190.670 17 504.680
3 2 26 013.340 25 785.410 26 256.710 26 038.200 26 038.200
4 3 34 683.460 34 380.140 35 008.430 34 716.910 34 718.110 34 596.030 34 596.030
5 4 43 352.763 42 974.430 43 759.600 43 395.540 43 398.265 43 244.392 43 244.392
6 5 52 021.106 51 568.529 52 510.563 52 073.470 52 078.631 51 891.662 51 891.662
7 6 60 688.210 60 162.076 61 260.734 60 751.242 60 759.489 60 538.443 60 538.443
8 7 69 353.880 68 755.025 70 010.208 69 428.403 69 440.772 69 184.277 69 184.277
9 8 78 017.953 77 347.425 78 758.849 78 104..943 78 122.587 77 829.107 77 829.107
10 9 86 680.190 85 938.962 87 506.607 86 780.778 86 805.027 86 472.805 86 472.805
11 10 95 340.443 94 529.761 96 253.318 95 455.814 95 488.131 95 115.214 95 115.214
12 11 103 998.481 103 119.703 104 998.886 104 130.010 104 171.962 103 756.254 103 756.254
13 12 112 654.059 111 708.707 113 743.241 112 803.258 112 856.585 112 395.756 112 395.756
14 13 121 307.237 120 296.630 122 486.173 121 475.496 121 542.113 121 033.586 121 033.586
15 14 129 957.471 128 883.644 131 227.927 130 146.799 130 228.419 129 669.703 129 669.703
16 15 138 604.670 137 469.287 139 967.903 138 816.739 138 915.603 138 303.496 138 304.065
17 16 147 248.826 146 053.574 148 706.124 147 485.360 147 603.963 146 935.424 146 936.284
18 17 155 889.867 154 636.867 157 442.862 156 152.743 156 293.317 155 565.312 155 566.394
19 18 164 527.308 163 218.602 166 177.725 164 818.845 164 983.881 164 192.884 164 194.278
20 19 173 161.061 171 798.990 174 910.596 173 483.466 173 675.392 172 817.892 172 819.679
21 20 181 791.104 180 377.768c 183 641.461 182 146.473 182 368.218 181 440.422 181 442.696
22 21 190 417.024 188 955.100 192 370.013 190 807.831 191 062.029 190 060.149 190 062.937
23 22 199 038.846 197 530.555 201 096.366 199 467.559 199 757.068 198 677.070 198 680.500
24 23 207 656.434 206 104.447 209 820.363 208 125.491 208 453.365 207 291.046 207 295.249
25 24 216 269.674 214 676.530 218 541.803 216 781.621 217 150.932 215 902.003 215 907.102
26 25 224 878.354 223 246.826 227 260.799 225 435.849 225 849.671 224 509.835 224 515.940
27 26 233 482.392 231 815.250 235 977.181 234 088.125 234 549.636 233 114.404 233 121.696
28 27 242 081.680 240 381.664 244 690.701 242 738.309 243 250.734 241 715.637 241 724.217
29 28 250 676.140 248 946.150 253 401.388 251 386.448 251 953.108 250 313.498 250 323.521
30 29 259 265.708 257 508.601 262 109.072 260 032.391 260 656.587 258 907.935 258 919.578
31 30 267 850.163 266 068.926 270 813.740 268 676.136 269 361.196 267 498.881 267 512.332
32 31 276 429.652 274 627.141 279 515.045 277 317.492 278 066.738 276 086.286 276 101.741
33 32 285 003.841 283 183.216 288 213.225 285 956.591 286 773.178 284 670.169 284 687.756
34 33 293 572.990 291 736.891 296 908.304 294 593.245 295 480.897 293 250.547 293 270.510
35 34 302 136.898 300 288.319 305 599.588 303 227.298 304 189.120 301 827.305 301 849.816
36 35 310 695.427 308 837.526 314 287.237 311 858.781 312 898.199 310 400.543 310 425.797
37 36 319 248.753 317 384.449 322 971.226 320 487.696 321 607.695 318 970.615 318 998.776
38 37 327 797.050 325 928.802 331 651.457 329 113.825 330 317.826 327 536.993 327 568.310
39 38 336 339.886 334 470.616 340 327.923 337 737.433 339 028.235 336 099.791 336 134.374
40 39 344 877.468 343 010.149 349 000.227 346 358.137 347 738.994 344 659.995 344 698.049
41 40 353 409.883 351 547.259 357 668.802 354 975.868 356 449.732 353 216.538 353 258.418
42 41 361 937.203 360 081.665 361 770.522 361 816.048
sequence V093 V126 V131 V089 V006 V096 V097

Notes.

(a)

The K quantum number notation is defined in the text below Eq. (A.1).

(b)

All frequencies for J″ > 3 (unless otherwise marked) are experimental measurements with estimated. uncertainty of 0.05 MHz. The frequencies for J″ = 0 to 3 are hyperfine removed frequencies evaluated by Koput.

(c)

Calculated from a J(J + 1) power series fit to the sequence.

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