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Table A.1
Parameters of the linear rotor-type, J(J + 1) power series fitted to the assigned line sequences.
| Ka | Nameb | Irelc | Nind | Nreje | sf (MHz) | Bg (MHz) | DJ (kHz) | HJ (Hz) | LJ (mHz) | PJ (μHz) | P12 (nHz) | P14 (pHz) | P16 (fHz) | P18 (aHz) |
| νb = 0 , m = 0 (gs): Evib = 0 cm -1 | ||||||||||||||
| 0 | V093: | 0.885 | 41 | 1 | 0.046 | 4335.6996 (13) | 8.4815 (43) | 0.1971 (58) | 0.0728 (33) | –0.00909 (69) | ||||
| 1L | V126: | 0.842 | 38 | 2 | 0.048 | 4297.6203 (10) | 3.3744 (21) | 0.1133 (16) | –0.00393 (41) | |||||
| 1U | V131: | 0.819 | 38 | 2 | 0.062 | 4376.1857 (14) | 4.2752 (30) | –0.0053 (24) | 0.00245 (67) | |||||
| 2L | V089: | 0.833 | 38 | 1 | 0.055 | 4339.69609 (82) | 3.28715 (94) | 0.03891 (31) | ||||||
| 2U | V006: | 0.901 | 38 | 1 | 0.052 | 4339.6811 (16) | –2.8764 (56) | –0.1690 (77) | –0.0676 (47) | 0.0079 (10) | ||||
| 3L | V096: | 0.727 | 35 | 4 | 0.063 | 4324.6816 (20) | 5.1755 (65) | –0.2787 (86) | 0.1698 (50) | –0.0156 (10) | ||||
| 3U | V097: | 0.726 | 35 | 4 | 0.054 | 4324.6762 (18) | 5.1686 (55) | –0.1769 (74) | 0.1479 (43) | –0.01455 (89) | ||||
| νb = 0, m = 1 E : Evib = 8.4 cm -1 | ||||||||||||||
| 0a | V107: | 0.808 | 22 | 0 | 0.051 | 4357.5774 (71) | 132.34 (14) | 86.4 (14) | 226.1 (67) | –665. (17) | 719. (21) | –298. (11) | ||
| 0b | X107: | 0.808 | 20 | 0 | 0.056 | 4348.7 (10) | 116.2 (37) | 146.2 (74) | –125.4 (87) | 71.4 (65) | –25.9 (29) | 5.39 (74) | –0.493 (81) | |
| –1 | V101: | 0.836 | 39 | 1 | 0.050 | 4282.7615 (32) | –3.118 (26) | 9.39 (10) | –10.67 (19) | 6.64 (21) | –2.59 (13) | 0.590 (44) | –0.0593 (59) | |
| 1 | V098: | 0.846 | 36 | 5 | 0.048 | 4284.5720 (42) | –35.940 (44) | –45.38 (21) | 49.98 (57) | –45.27 (87) | 29.62 (81) | –12.71 (44) | 3.16 (12) | –0.342 (15) |
| –2 | not assigned | |||||||||||||
| 2 | V010: | 0.660 | 31 | 2 | 0.042 | 4350.3415 (23) | –2.325 (15) | –0.065 (46) | –0.290 (64) | 0.284 (43) | –0.109 (11) | |||
| –3 | V005: | 0.800 | 36 | 2 | 0.058 | 4343.3487 (25) | 0.096 (11) | 0.288 (25) | –0.381 (25) | 0.202 (12) | –0.0848 (22) | |||
| 3 | V012: | 0.642 | 34 | 3 | 0.049 | 4356.1489 (11) | 1.6845 (24) | –0.0204 (19) | 0.00189 (52) | |||||
| νb = 0 , m = −2 E : Evib = 36.8 cm -1 | ||||||||||||||
| 0 | V119: | 0.774 | 36 | 1 | 0.050 | 4356.2099 (29) | 2.431 (15) | 0.837 (33) | –2.676 (29) | |||||
| –1 | V008: | 0.708 | 38 | 2 | 0.062 | 4353.2529 (11) | 1.0831 (14) | 0.0 | 0.00928 (84) | –0.00378 (31) | ||||
| 1 | V180: | 0.807 | 40 | 0 | 0.188 | 4350.771 (14) | –40.79 (16) | –39.36 (81) | –24.5 (22) | 74.5 (34) | –69.5 (32) | 34.7 (17) | –9.27 (54) | 1.045 (69) |
| –2 | not assigned | |||||||||||||
| 2 | V100: | 0.805 | 39 | 0 | 0.084 | 4276.5950 (66) | –51.195 (68) | –64.24 (33) | 63.79 (84) | –50.5 (12) | 29.3 (11) | –11.35 (59) | 2.60 (17) | –0.262 (20) |
| –3 | V024: | 0.473 | 35 | 3 | 0.055 | 4366.9265 (12) | 1.9129 (27) | –0.0098 (22) | 0.00672 (61) | |||||
| 3a | V106: | 0.523 | 21 | 0 | 0.043 | 4373.6038 (50) | 110.306 (69) | 93.71 (41) | –32.2 (12) | –11.7 (16) | 10.81 (88) | |||
| 3b | X106: | 0.884 | 18 | 0 | 0.052 | 4370.20 (59) | 103.8 (16) | 95.6 (24) | –55.9 (22) | 20.9 (11) | –4.49 (32) | 0.438 (38) | ||
| νb = 0 , m = 3 L (K = 0,J = 0,1 = A1,A2) : Evib = 80.3 cm -1 | ||||||||||||||
| 0 | V017: | 0.556 | 38 | 2 | 0.061 | 4361.0342 (19) | 0.6664 (66) | 0.0255 (94) | 0.0843 (57) | –0.0269 (12) | ||||
| –1 | V137: | 0.654 | 37 | 2 | 0.093 | 4376.0833 (78) | –11.011 (83) | 3.34 (41) | –25.5 (11) | 21.8 (17) | –17.3 (16) | 11.56 (91) | –4.15 (27) | 0.576 (34) |
| 1 | V082: | 0.485 | 39 | 0 | 0.070 | 4362.15134 (58) | 1.68176 (26) | |||||||
| –2 | not assigned | |||||||||||||
| 2 | V030: | 0.399 | 35 | 3 | 0.067 | 4369.5669 (10) | 1.9458 (12) | –0.00228 (41) | ||||||
| 3 | V040: | 0.634 | 33 | 2 | 0.064 | 4378.65685 (60) | 2.06406 (30) | |||||||
| νb = 0 , m = 3 U (K = 0,J = 1,0 = A2,A1) : Evib = 79.7 cm -1 | ||||||||||||||
| 0 | V018: | 0.540 | 39 | 2 | 0.046 | 4361.4499 (14) | 0.5247 (49) | 0.0221 (69) | 0.0949 (42) | –0.02898 (93) | ||||
| 1 | V020: | 0.491 | 36 | 3 | 0.044 | 4363.55034 (68) | 1.72074 (80) | –0.00110 (27) | ||||||
| –1 | not assigned | |||||||||||||
| 2 | V029: | 0.424 | 34 | 4 | 0.057 | 4369.57115 (94) | 1.9779 (10) | 0.00072 (36) | ||||||
| –2 | not assigned | |||||||||||||
| 3 | very strongly perturbed | |||||||||||||
| νb = 0 , m = 4 E : Evib = 140.6 cm-1 | ||||||||||||||
| 0 | V025: | 0.416 | 37 | 3 | 0.052 | 4368.7341 (11) | 1.5662 (25) | 0.0039 (21) | 0.00218 (57) | |||||
| νb = 0 , m = −5 E : Evib = 217.5 cm -1 | ||||||||||||||
| 0 | V142: | 0.297 | 38 | 1 | 0.049 | 4377.7029 (11) | 1.8930 (23) | –0.0136 (19) | 0.00256 (51) | |||||
| νb = 1 , m = 0: Evib = 182.2 cm -1 | ||||||||||||||
| 0 | V094: | 0.391 | 41 | 0 | 0.050 | 4335.3010 (15) | 7.8017 (47) | 0.2011 (63) | 0.0443 (37) | –0.00561 (76) | ||||
| 1L | V127: | 0.373 | 38 | 2 | 0.052 | 4297.1113 (11) | 3.2544 (22) | 0.0971 (17) | –0.00294 (44) | |||||
| 1U | V132: | 0.365 | 36 | 3 | 0.048 | 4377.6225 (11) | 4.2356 (24) | 0.0116 (19) | 0.00223 (53) | |||||
Notes.
(a)
The value of the Ka or K quantum number following, where possible, the notation of Koput (1986) and described further in the text following Eq. (A.1).
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