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Table A.3

Level energies and TEC as used in the final AUTOSTRUCTURE calculation for V III.

Configuration Term J Energy (cm-1) Energy (cm-1) TEC (cm-1)
expa AUTOS this work

3d3 a 4F 3/2 0.00 0.00
5/2 145.50 172.84
7/2 341.50 406.80
9/2 583.80 695.19
3d3 a 4P 1/2 11 513.80 13 652.20 –2497
3/2 11 591.80 13 742.40
5/2 11 769.70 13 946.95
3d3 a 2G 7/2 11 966.30 14 416.19 –2809
9/2 12 187.00 14 673.74
3d3 a 2P 3/2 15 550.30 19 114.04 –3844
1/2 15 579.80 19 129.74
3d3 a 2D2 3/2 16 330.50 20 100.91 –4152
5/2 16 374.70 20 146.12
3d3 a 2H 9/2 16 810.90 20 078.30 –3621
11/2 16 977.60 20 266.61
3d3 a 2F 7/2 27 727.80 33 089.20 –5714
5/2 27 846.80 33 235.15
3d3 b 2D1 5/2 42 267.40 51 583.88 –9671
3/2 42 371.20 51 719.41
3d2(3F)4s b 4F 3/2 43 942.49 42 602.54 987
5/2 44 110.04 42 776.48
7/2 44 345.82 43 020.31
9/2 44 646.96 43 331.75
3d2(3F)4s b 2F 5/2 49 327.74 49 213.89 –232
7/2 49 805.29 49 701.01
3d2(1D)4s c 2D 5/2 56 160.42 57 018.51 –1315
3/2 56 256.75 57 375.49
3d2(3P)4s b 4P 1/2 56 529.30 57 113.98 –942
3/2 56 669.05 57 121.34
5/2 56 922.50 57 648.95
3d2(3P)4s b 2P 1/2 61 578.74 63 473.37 –2243
3/2 61 777.15 63 680.34
3d2(1G)4s b 2G 9/2 63 303.12 64 977.65 –2011
7/2 63 315.05 64 979.63

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