Table D.1
Abbreviated reaction list.
| Reactiona | A | B | C | Reference |
|
|
||||
| S + H2 → SH + H | 4.20 × 10-10 | 0.00 | 10494.00 | (1)c |
| SH + H2 → H2S + H | 7.36 × 10-13 | 2.31 | 6862.00 | (2) |
| SH + H → S + H2 | 1.39 × 10-10 | –0.18 | 697.00 | (1) |
| S + OH → SO + H | 6.59 × 10-11 | 0.00 | 0.00 | (3) |
| SH + O → SO + H | 1.58 × 10-10 | 0.00 | 0.00 | (3;4) |
| S+ + H2 → SH+ + H | 2.20 × 10-10 | 0.00 | 9860.00 | (5)c |
| S+ + H2 → H2S+ + hν | 1.00 × 10-17 | –0.20 | 0.00 | (6) |
| SH+ + H2 → H2S+ + H | 1.90 × 10-10 | 0.00 | 6380.00 | (5)c |
| SH+ + H2 → H3S+ + hν | 2.40 × 10-16 | –0.80 | 0.00 | (7) |
| SH+ + H → S+ + H2 | 1.10 × 10-10 | 0.00 | 0.00 | (5) |
| H2S+ + H2 → H3S+ + H | 1.40 × 10-11 | 0.00 | 2900.00 | (5)c |
| H2S+ + H → SH+ + H2 | 2.00 × 10-10 | 0.00 | 0.00 | (5) |
| H3S+ + H → H2S+ + H2 | 6.00 × 10-11 | 0.00 | 0.00 | (5) |
| CS+ + H2 → HCS+ + H | 4.50 × 10-10 | 0.00 | 0.00 | (8) |
| S+ + CH → CS+ + H | 6.20 × 10-10 | –0.00 | 0.00 | (9)c |
| SH+ + C → CS+ + H | 9.90 × 10-10 | 0.00 | 0.00 | (9) |
|
1.40 × 10-9 | 0.00 | 0.00 | (9) |
|
2.60 × 10-9 | 0.00 | 0.00 | (9) |
| SH+ + e → S + H | 2.00 × 10-7 | –0.50 | 0.00 | (9) |
| H2S+ + e → SH + H | 2.40 × 10-7 | –0.72 | 0.00 | (10)c |
| H2S+ + e → S + H + H | 2.40 × 10-7 | –0.72 | 0.00 | (10)c |
| H2S+ + e → H2S + hν | 1.10 × 10-10 | –0.70 | 0.00 | (9) |
| H3S+ + e → SH + H + H | 3.02 × 10-7 | –0.50 | 0.00 | (11) |
| H3S+ + e → H2S + H | 8.84 × 10-8 | –0.50 | 0.00 | (11; 12) |
| H3S+ + e → SH + H2 | 7.80 × 10-8 | –0.50 | 0.00 | (11; 12) |
| H3S+ + e → S + H2 + H | 5.20 × 10-8 | –0.50 | 0.00 | (11; 12) |
| HCS+ + e → CH + S | 7.86 × 10-7 | –0.57 | 0.00 | (13) |
| HCS+ + e → CS + H | 1.84 × 10-7 | –0.57 | 0.00 | (13) |
| O + H2S → SH + OH | 7.90 × 10-12 | 1.00 | 1737.00 | (1)c |
|
3.70 × 10-9 | 0.00 | 0.00 | (14; 15)c |
|
|
||||
| Photoprocessb | ζ 0 | γ | Reference | |
|
|
||||
| S + hν → S+ + e | 4.40 × 10-10 | 2.58 | (16) | |
| SH + hν → S + H | 6.50 × 10-10 | 1.42 | (16) | |
| H2S + hν → SH + H | 1.00 × 10-9 | 1.87 | (16; 17) | |
| H2S + hν → S + H2 | 1.00 × 10-9 | 1.87 | (16; 17) | |
| CS + hν → C + S | 6.30 × 10-10 | 2.03 | (16) | |
| SO + hν → S + O | 2.40 × 10-9 | 1.95 | (16) | |
| HCS+ + hν → CS+ + H | 7.00 × 10-10 | 1.70 | (18) | |
Notes.
Reference. (1) Manion et al. (2013); (2) Peng et al. (1999); (3) Demore et al. (1997); (4) Tsuchiya et al. (1994); (5) Millar et al. (1986); (6) Herbst et al. (1989); (7) Millar & Herbst (1990); (8) Decker et al. (2001); (9) Prasad & Huntress (1980); (10) Hellberg et al. 2005; (11) Abouelaziz et al. (1992); (12) Kaminska et al. (2008); (13) Montaigne et al. (2005); (14) Kim et al. (1974); (15) Anicich et al. (1975); (16) van Dishoeck et al. (1988); (17) van Dishoeck (2006); (18) estimate.
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