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Table 1

Atomic and molecular features used to classify C, M- and S-type stars.

λ (Å) Feature Comment

4861 Hβ F-line Fraunhofer F-line. Seen in emission in some of our stars.
4959 [O III] Forbidden emission line of doubly ionised oxygen, ~1/3 strength of the 5007 Å line. Seen in some of our stars.
5007 [O III] Forbidden emission line of doubly ionised oxygen. Seen in some of our stars.
5165 C2 Degrades blueward from bandhead.
5167 Mg I Visible in all G, K, and M-type stars until M4 III or M6.5 V; greatly enhanced in dwarfs.
5173 Mg I See comments for Mg I 5167 Å.
5184 Mg I See comments for Mg I 5167 Å.
5211 MgH Broad absorption feature in M-type dwarfs; degrades toward the violet.
5298 ZrO Several ZrO bands beginning at 5298 Å. Visible in mid S-type stars.
5577 [O I] Telluric oxygen emission line.
5636 C2 Degrading blueward.
5730 CN
5810 TiO Visible at M2 to M3.
5862 TiO Visible at M0 to M1.
5890 Na I D-line Visible in all G-, K- and early M-type stars. Greatly enhanced in dwarfs; overwhelmed in M-type giants by M2.
5896 Na I D-line As above.
6005 C2 Molecular carbon feature degrading blueward.
6059 C2 Molecular carbon feature degrading blueward.
6132 ZrO Several ZrO bands beginning at 6132 Å. Increasing in strength with later spectral type.
6159 TiO Bandhead degrades redward.
6162 Ca I Enhanced in M-type dwarfs.
6206 CN
6300 [O I] Telluric oxygen line.
6332 CN
6363 [O I] Telluric oxygen emission line.
6385 CaH Band used as an M-type dwarf indicator.
6478 CN
6532 VO Seen in S-type stars.
6548 [N II] Forbidden emission line of singly ionised nitrogen, ~1/3 strength of the 6583 Å line. Seen in some of our stars.
6563 Hα C-line Fraunhofer C-line. Seen in emission or absorption in some of our stars.
6569 TiO Several TiO bands beginning at 6569 Å that are marginally visible in early M-types.
6583 [N II] Forbidden emission line of singly ionised nitrogen. Seen in some of our stars.
6631 CN
6716 [S II] Forbidden emission line of singly ionised sulphur. Seen in some of our stars.
6731 [S II] As above.
6867 O2B-band Fraunhofer B-line. A telluric absorption feature.
6908 CaH Discussed with CaH (6946 Å) below.
6925 CN
6933 ZrO Seen in S-type stars. Clearly visible by mid-S.
6946 CaH Strongest in early M-type dwarfs. Bands of CaH serve to widen and deepen the TiO bands in this region.
Blended with the O2B-band.
6988 ZrO Seen in S-type stars. Clearly visible by mid-S.
7054 TiO Clearly visible at K5; bandhead degrading redward.
7088 CN
7186 H2O Telluric band. Degrading redward.
7198 TiO Distinct from M1.
7219 TiO Distinct from M1.
7259 CN
7269 TiO Distinct from M1. Combined with TiO bands at 7198 and 7219 Å creates a distinctive triple dip feature.
7334 VO Several bands of VO beginning at 7334 Å and increasing in strength from late M-type stars.
7437 CN
7590 TiO Blended into the O2 A-band.
7594 O2 A-band Fraunhofer A-line. A telluric absorption feature.
7628 TiO Several TiO bands follow on from 7666 Å, creating a wide depression in the region immediately following the telluric.
O2 feature. Seen in M-type stars of all luminosities. First seen around M2 becoming very pronounced by mid-M.
7861 TiO
7876 CN Several CN bands follow on from 7876 Å. Obvious in supergiants, weaker in giants; not seen in dwarfs.
8026 CN Several CN bands follow on from 8026 Å. Obvious in supergiants, weaker in giants; not seen in dwarfs.
8183 Na I Strong in dwarf stars.
8195 Na I As above.
8227 H2O Weak telluric feature. Degraded to the red.
8498 Ca II Strongest in late K-type through mid M-type stars; strongest in giants and super giants; weaker in dwarfs.
8542 Ca II As above.
8662 Ca II As above.

Notes. The wavelengths of some of the major telluric features seen in our spectra are also listed. The most important of these features have been marked on the spectra. Comments are included, where relevant, from the work of Turnshek et al. (1985), Kirkpatrick et al. (1991) and our own observations. Also included are the wavelengths of some important emission lines seen in some of our spectra.

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